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Synthesis,Crystal Structure and Spectroscopic Properties of[Ag(pba)(Et-dtc)]·p-xylene
HUANG Ting-hong, WANG Miao, MA Kai, YANG Kun-guo, HUANG Ying-da, YOU Teng-li, WANG Xiu-jian
Journal of Guangxi Normal University(Natural Science Edition). 2011, 29 (3):
43-46.
[Ag(pba)(Et-dtc)]·p-xylene (pba=N,N-bis((diphenylphosphino)methyl)benzenamine,Et-dtc=N-ethyldithiocarbamate) has been prepared in 4 mL CH3CN/p-xylene(1∶1) and structurally characterized.The crystal is of triclinic,space group P-1 with a=1.003 9(2) nm,b=1.026 22(2) nm,c=1.931 3(4) nm;α=86.404(3)°,β=75.142(2)°,γ=67.018(2)°,Z=2.The Ag(Ⅰ) atom in the title compound is four coordinated by two P atoms ofN,N-bis((diphenylphosphino)methyl)benzenamine and two S atoms of two N-ethyl dithiocarbamate,forming a tetrahedral geometry.In the crystal,the cationsare is linked by C—H…π interactions,forming chains along the a axis(φ=168.7°,Dlin=0.288 1 nm).The title complex is characterized by IR and fluorescence.
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