Journal of Guangxi Normal University(Natural Science Edition) ›› 2011, Vol. 29 ›› Issue (3): 43-46.

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Synthesis,Crystal Structure and Spectroscopic Properties of[Ag(pba)(Et-dtc)]·p-xylene

HUANG Ting-hong, WANG Miao, MA Kai, YANG Kun-guo, HUANG Ying-da, YOU Teng-li, WANG Xiu-jian   

  1. College of Chemistry and Chemical Engineering,Guangxi NormalUniversity,Guilin Guangxi 541004,China
  • Received:2011-05-08 Online:2011-08-20 Published:2018-12-03

Abstract: [Ag(pba)(Et-dtc)]·p-xylene (pba=N,N-bis((diphenylphosphino)methyl)benzenamine,Et-dtc=N-ethyldithiocarbamate) has been prepared in 4 mL CH3CN/p-xylene(1∶1) and structurally characterized.The crystal is of triclinic,space group P-1 with a=1.003 9(2) nm,b=1.026 22(2) nm,c=1.931 3(4) nm;α=86.404(3)°,β=75.142(2)°,γ=67.018(2)°,Z=2.The Ag(Ⅰ) atom in the title compound is four coordinated by two P atoms ofN,N-bis((diphenylphosphino)methyl)benzenamine and two S atoms of two N-ethyl dithiocarbamate,forming a tetrahedral geometry.In the crystal,the cationsare is linked by C—H…π interactions,forming chains along the a axis(φ=168.7°,Dlin=0.288 1 nm).The title complex is characterized by IR and fluorescence.

Key words: synthesis, structure, spectroscopic properties

CLC Number: 

  • O641
[1] E′RIC F,ANDREAS D,PIERRE D H.Small metal-containing oligomers using M2(dmpm)x and M2(dmb)y luminescent buildingblocks (M=Cu,Ag;x=2,3;y=1,2)[J].European Journal of Inorganic Chemistry,2004,22:4420-4429.
[2] XU Feng-bo,LI Qing-shan,ZENG Xian-shun,et al.Bimetallocyclophanes formed by the π-π stacking interaction approach and fluorescent chemosensing behavior[J].Organometallics,2004,23(4):632-634.
[3] STANG P J,CAO D H,SAITO S,et al.Self-assembly of cationic,tetranuclear,Pt(Ⅱ) and Pd(Ⅱ) macrocyclic squares.X-ray crystal structure of [Pt2+(dppp)(4,4′-bipyridyl)·cntdot]2-OSO2CF3]4[J].Journal of American Chemical Society,1995,117(23):6273-6283.
[4] YU Shu-yan,ZHANG Zhong-xing,CHENG Chung-chin,et al.A chiral luminescent Au16 ring self-assembled from achiral components[J].Journal ofAmerican Chemical Society,2005,127(51):17994-17995.
[5] 邹红丽,张敏敏,李家元,等.[Cu(phen)(PPh3)Cl]2·H2O的合成和晶体结构[J].广西师范大学学报:自然科学版,2010,28(2):74-77.
[6] McKEAGE M J,LENUSHKA M,BERNERS-PRICE S J.Mechanisms of cytotoxicity and antitumor activity of gold(Ⅰ) phosphine complexes:the possible role of mitochondria[J].Coordination Chemistry Reviews,2002,232:127-135.
[7] SMITH M B,DALE S H,COLES S J,et al.Isomeric dinuclear gold(Ⅰ) complexes with highly functionalised ditertiary phosphines:self-assembly of dimers,rings and 1-D polymeric chains[J].Cryst Eng Comm,2006,8(2):140-149.
[8] JACOBSON R A.SMART,SAINT and SHELXTL[CP/DK].Madison,USA:Bruker AXS Inc,1998.
[9] SHELDRICK G M.SHELXS 97 and SHELXL 97[CP/DK].Go¨ttingen,Germany:University of Go¨ttingen,1997.
[10] SHANG Jing,HUANG Li-li,HUANG Ting-hong,et al.Bis{N,N-bis[(diphenylphos-phanyl)methyl]aniline-[kap-pa]2P,P′} copper(Ⅰ) tetrafluoridoborate[J].Acta Crystallographica Section E,2011,67(1):m96.
[11] CUTTELL D G,KUANG Shan-ming,FANWICK P E,et al.Simple Cu(Ⅰ) complexes with unprecedented excited-state lifetimes[J].Journal of American Chemical Society,2002,124:6-7.
[12] RADER R A,MCMILLIN D R,BUCKNER M T,et al.Photostudies of 2,2′-bipyridine bis(triphenylphosphine)copper(1+),1,10-phenanthroline bis(triphenylphosphine)copper(1+),and 2,9-dimethyl-1,10-phenanthroline bis(triphenylphosphine)copper(1+) in solution and in rigid,low-temperature glasses,simultaneous multiple emissions from intraligand and charge-transfer states[J].Journal of American Chemical Society,1981,103:5906-5912.
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