Journal of Guangxi Normal University(Natural Science Edition) ›› 2023, Vol. 41 ›› Issue (3): 210-220.doi: 10.16088/j.issn.1001-6600.2022050903

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Preparation of CuO/MIL(Cr, Cu) Composite and Its Performance in Fenton-like Catalytic Degradation of Phenol

YANG Wen1, SU Yingjie1, HOU Dongrui2, LUO Jing1, SUN Qinggong1, ZHANG Mengyang2, YANG Hao2, WANG Jianfeng2*   

  1. 1. School of Chemical Engineering, Zhengzhou University, Zhengzhou Henan 450007, China;
    2. School of Ecology and Environment, Zhengzhou University, Zhengzhou Henan, 450007, China
  • Received:2022-05-09 Revised:2022-05-17 Online:2023-05-25 Published:2023-06-01

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Abstract: CuO/MIL(Cr, Cu) heterogeneous Fenton-like catalysts were synthesized by hydrothermal calcination. The CuO/MIL(Cr, Cu) composite was characterized by XRD, FT-IR, SEM, XPS, BET, etc. The results showed that CuO was uniformly dispersed on the surface of the metal-organic framework MIL(Cr, Cu). In addition, the performance of different catalysts for the catalytic degradation of phenol were compared. The results of degradation experiments showed that when the catalyst dosage was 0.3 g/L, the H2O2 concentration was 50 mmol/L, pH=6, and the initial substrate concentration was 30 mg/L, the CuO/MIL(Cr, Cu) composite had the best degradation efficiency as high as almost 100%, better than that of CuO and MIL-101(Cr). Finally, the radical quenching experimentand EPR test proved that ·OH was the main active radical in the catalytic system, and the possible catalytic mechanism was proposed. CuO/MIL(Cr, Cu) composite can degrade phenolic pollutants in the near-neutral range and have good application prospects.

Key words: heterogeneous catalyst, Fenton-like, metal organic framework, copper oxide, phenol wastewater

CLC Number:  X703;TQ426.94
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