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Triterpenoids from the Aerial Part of Rabdosia stracheyi
CHANG Yanling, LIANG Xiaoqin, HUANG Yan, PAN Liwei, HOU Ping, REN Chenyang, LI Jun
Journal of Guangxi Normal University(Natural Science Edition). 2023, 41 (4):
158-164.
DOI: 10.16088/j.issn.1001-6600.2022061702
To study the compounds of Rabdosia stracheyi, twelve triterpenoids were isolated from the aerial part of R. stracheyi by means of various column chromatographic techniques, including silica gel, ODS, Sephadex LH-20 and preparative RP-HPLC. The structures of the isolated triterpenoids were determined on the basis of analyses of spectroscopic methods (1H- and 13C-NMR spectroscopy), high-resolution electrospray ionization mass spectrometry (HR-ESI-MS), and comparison of their spectroscopic data with previously reported data. The triterpenoids were identified as friedelinol (1), oleanolic acid (2), 3β-hydroxy-oleana-11, 13(18) -dien-28-oic acid (3), 2α, 3α-dihydroxy olean-12-en-28-oic acid (4), 2a, 3a, 24-trihydroxyolean-12-en-28-olic acid (5), 2α, 3β, 24-trihydroxy olea-12en-28oic acid (6), cleistocalyxin (7), uvaol (8), 2α-hydroxy ursolicacid (9), methyl 2a, 3a, 24-trihydroxy ursa-12, 20(30)-dien-28 oate (10), maquatic acid (11) and 2α, 3β, 24-trihydroxyurs-12, 20(30)-dien-oic acid (12). All compounds were isolated from R. stracheyi for the first time.
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