Journal of Guangxi Normal University(Natural Science Edition) ›› 2013, Vol. 31 ›› Issue (2): 76-80.

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Synthesis,Crystal Structure and Magnetic Properties of [Mn3(oba)3(DMF)4]

SHENG Liang-bing1,2, SHEN Yan-ling1,2, XIONG Bo-pi1,2, ZOU Hua-hong1,2, LIANG Fu-pei1,2   

  1. 1.College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China;
    2.State Key Laboratory Cultivation Base for the Chemistry and Molecular Engineering of Medicinal Resources, Guilin Guangxi 541004,China
  • Received:2013-03-11 Online:2013-06-20 Published:2018-11-26

Abstract: [Mn3(oba)3(DMF)4](oba=1,4-benzenedicarboxylate),DMF=dimethylformamide) hasbeen prepared and structurally characterized.The crystal is of triclinic,spacegroup P1 with a=0.991 23(2) nm,b=1.279 15(8) nm,c=1.66275(10) nm,α=74.340(5)°,β=89.042(5)°,γ=87.280(5)°,Z=2.The Mn1 atomin the title complex is six coordinated by two O atoms of DMF and four O atoms of oba,forming an oxtrahedral geometry.The Mn2 atom coordinated to six O atoms ofoba with oxtrahedral geometry.The complex is a 6-connected topology structure.The title complex is characterized by IR,TG,and magnetic properties analyses.

Key words: synthesis, structure, magnetic properties

CLC Number: 

  • O641
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