Journal of Guangxi Normal University(Natural Science Edition) ›› 2013, Vol. 31 ›› Issue (2): 69-75.

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Hydrogen-bonding Directed Three-dimensional Supramolecular Structure in Catena-((μ2-4,4'-bipyridine)-tetraaqua-cobalt(Ⅱ) bis (2-methylbenzimidazolium-1,3-diacetate) dehydrate): Synthesis and Crystal Structural Characterization

ZENG Jian-qiang, LIANG Guang-ming, HUANG Ying-da, YANG Kun-guo, GUI Liu-cheng, NI Qing-ling   

  1. College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2012-12-09 Online:2013-06-20 Published:2018-11-26

Abstract: The title compound,{[Co(4,4'-bipy)(H2O)4](pda)2(H2O)2}n,was obtained by the hydrothermal reaction of cobalt acetate with 3-carboxymethyl-1,3-(2-methylbenzimidazolium)-1-acetate (Hpda) and4,4'-bipyridine (4,4'-bipy).X-ray single crystal diffraction shows that the asymmetric unit of the title compound contains half a Co2+ ion,half a 4,4'-bipy molecule,one counter anion pda-,two coordinated water molecules andone lattice water molecule.Co2+ ions are bridged by 4,4'-bipy moleculesresulting in a one-dimensional coordination chain,{[Co(4,4'-bipy)(H2O)4]2+}n,in which Co2+ center is six-coordinated by two nitrogen atoms from different 4,4'-bipy molecules and four oxygen atoms from coordinated water molecules.In the solid state,two-dimensional undulating layers are constructed through hydrogen bonds between pda- anions,coordinated water and crystallization water molecules,while neighboring hydrogen-bonding layers are further pillared by 4,4'-bipy into a three-dimensional supramolecular structure which contains one-dimensional channels.

Key words: coordination polymer, supramolecule, hydrogen bond, crystal structure

CLC Number: 

  • O641.4
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