Journal of Guangxi Normal University(Natural Science Edition) ›› 2015, Vol. 33 ›› Issue (1): 93-98.doi: 10.16088/j.issn.1001-6600.2015.01.015

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Synthesis and Crystal Structures of Zn(Ⅱ) and Cu(Ⅱ) Complexes of 2,2′-dihydroxy[1,1′-binaphthalene]-3,3′-dicarbonylbis(salicylaldehydehydrazone)

JIANG Li-ping1, HUANG Wan-yun2, LIU Dong-cheng3, LIANG Fu-pei4   

  1. 1. Science and Technology Department, Guangxi Normal University, Guilin Guangxi 541004, China;
    2. College of Pharmacy, Guilin Medical University, Guilin Guangxi 541004, China;
    3. Personnel Division, Guangxi Normal University, Guilin Guangxi 541004, China;
    4. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin Guangxi 541004, China
  • Received:2015-01-21 Online:2015-03-15 Published:2018-09-17

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Abstract: The reactions of 2,2′-dihydroxy [1,1′-binaphthalene]-3,3′-dicarbonylbis(salicylaldehydehydrazone) (H4L) with Zn(Ⅱ) and Cu(Ⅱ) salts gave two new complexes {[Zn2L(DMSO)(H2O)]·2DMSO·2H2O}n (1) and [Cu2L(DMSO)2] (2). Complex 1 crystallizes in the triclinic space group Pī. Complex 2 crystallizes in the monoclinic space group C2/c. Complex 1 shows a one-dimensional structure with dinuclear subunits. Complex 2 presents a discrete dinuclear structure. The Zn(Ⅱ) ion in 1 is five-coordinated in square pyramidal geometry by one oxygen atom from one H2O molecule, two oxygen atoms and one nitrogen atom from one dihydrazone ligand, and one phenolic hydroxyl oxygen atom from another dihydrazone ligand. The Cu(Ⅱ) ion in 2 is coordinated by one oxygen atom from DMSO molecule, two oxygen atoms and one nitrogen atom from one dihydrazone ligand, forming a planar square geometry.

Key words: binaphthol, dihydrazone, complex, crystal structure, Zn(Ⅱ), Cu(Ⅱ)

CLC Number: 

  • O641
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