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广西师范大学学报(自然科学版) ›› 2020, Vol. 38 ›› Issue (4): 92-99.doi: 10.16088/j.issn.1001-6600.2020.04.011
谢婷婷, 谢瑶, 倪青玲*
XIE Tingting, XIE Yao, NI Qingling*
摘要: 用2种新的膦配体N,N′-二[(二苯基膦)亚甲基]-N,N′-二(4-吡啶甲基)-对苯二胺(L1)和N,N′-二[(二苯基膦)亚甲基]-N,N′-二(2-吡啶甲基)-对萘二胺(L2),与金盐[AuCl(THF)](THF=四氢呋喃)反应生成有机膦氯化金配合物;该配合物进一步在苯乙炔的作用下生成有机膦金炔配合物;金炔配合物与叠氮基三甲基硅烷反应得到三氮唑配合物。通过红外、核磁和X-射线单晶衍射对这些配合物进行表征,发现配合物中弱的Au-π作用对配合物的稳定性起着一定的作用。
中图分类号:
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