汲取液溶质反向扩散与正渗透中膜污染的相互关系研究

doi:10.16088/j.issn.1001-6600.2024052903

Abstract

Abstract: Membrane fouling poses a limitation to the application of forward osmosis (FO), and reverse solute flux (RSF) from the draw solutes further reduces the permeability of the membrane. Therefore, this study investigated the dynamic relationship between reverse solute flux and organic membrane fouling using typical inorganic draw solutions (DSs)(NaCl,NaHCO₃,NaH₂PO₄,NH₄Cl,CaCl₂). On one hand, the reverse solute flux directly interacted with the membrane fouling layer, affecting its configuration. For example, the reverse flux of Ca²⁺ from CaCl₂ draw solute readily crosslinked with sodium alginate (SA), forming a three-dimensional network structure that exacerbated membrane fouling. On the other hand, the formation of membrane fouling reduced the reverse flux of Ca²⁺ from CaCl₂ draw solute (5.8±1.6 mmol·m^-2·h^-1) while increasing the reverse diffusion of NH⁺₄ from NH₄Cl draw solution (129.2±12.8 mmol·m^-2·h^-1). Consequently, the water recovery using NH₄Cl as the draw solute (151.4±10.6 g) was lower than that using CaCl₂ (246.4±124.7 g). Furthermore, reverse solute flux altered the properties of the feed solute, leading to the dominance of different filtration mechanisms in the formation of membrane fouling, which subsequently impacts the degree of fouling.

Key words: forward osmosis, membrane fouling, reverse solute flux, draw solute, dynamic relationship

CLC Number: X52

ZHAI Siqi, CAI Wenjun, ZHU Su, LI Hanlong, SONG Hailiang, YANG Xiaoli, YANG Yuli. Dynamic Relationship Between Reverse Solute Flux and Membrane Fouling in Forward Osmosis[J].Journal of Guangxi Normal University(Natural Science Edition), 2024, 42(6): 30-39.

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Dynamic Relationship Between Reverse Solute Flux and Membrane Fouling in Forward Osmosis

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