Journal of Guangxi Normal University(Natural Science Edition) ›› 2012, Vol. 30 ›› Issue (3): 189-193.

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Synthesis,Crystal Structure and Characterization of One-Dimensional Au-Organophosphine Complex Based on Intermolecular Au…Au Interactions

WANG Xiu-jian, CONG Xin-yu, JIANG Xuan-feng, MA Kai, ZHANG Zhi-hao, ZENG Jian-qiang, NI Qing-ling   

  1. College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2012-05-15 Online:2012-09-20 Published:2018-12-04

Abstract: By the reaction of [AuCl(THT)] (THT=tetrahydrothiophene) and N,N,N′,N′-tetrakis ((diphenylphosphino) methyl)biphenyl-4,4′-diamine,a tetranuclearcomplex [Pbbaa(AuCl)4] was afforded.X-ray diffraction analysis shows thatadjacent molecules are bridged by intermolecular Au…Au interactions to form an one-dimensional chain.The 31P and 1H spectra of this complex are measured,while the solid state luminescence at 509 nm is ascribed to MLCT transition destabilized by intermolecular Au…Au interactions.

Key words: polyphosphine ligand, Au-P complex, crystal structure, photoluminescence

CLC Number: 

  • O641
[1] ERIC F,ANDREAS D,PIERRE D H.Small metal-containing oligomers using M2(dmpm)x and M2 (dmb)y luminescent building blocks (M=Cu,Ag;x=2,3;y=1,2)[J].European Journal of Inorganic Chemistry,2004,22:4420-4429.
[2] XU Feng-bo,LI Qing-shan,ZENG Xian-shun,et al.Bimetallocyclophanes formedby the π-π stacking interaction approach and fluorescent chemosensing behavior[J].Organometallics,2004,23(4):632-634.
[3] LU P,BOORMAN T C,SLAWIN A M Z,et al.Gold(Ⅰ)-mediated C—H activation of arenes[J].Journal of American Chemical Society,2010,132(16):5580-5581.
[4] GORIN D J,SHERRY B D,TOSTE F D.Ligand effects in homogeneous Aucatalysis[J].Chemical Reviews,2008,108(8):3351-3378.
[5] SCHMIDBAUR H,SCHIER A.Gold η2-coordination to unsaturated andaromatic hydrocarbons:the key step in gold-catalyzed organic transformations[J].Organometallics,2010,29(1):2-23.
[6] LI Xiu-ling,TAN Ming,ZHANG Ke-juan,et al.Dual luminescent tetranuclear organogold(Ⅰ) macrocycles of 5,5′-diethynyl-2,2′-bipyridine and their efficientsensitization of Yb(Ⅲ) luminescence[J].Inorganic Chemistry,2012,51(1):109-118.
[7] WANG Xiu-jian,GUI Liu-cheng,NI Qing-ling,et al.π-Stacking induced complexes with Z-shape motifs featuring a complementary approach between electron-rich arene diamines and electron-deficient aromatic N-heterocycles[J].Cryst Eng Comm,2008,10:1003-1010.
[8] DURRAN S E,SMITH M B,SLAWIN A M Z,et al.The synthesis and co-ordinationchemistry of new functionalised pyridylphosphines derived from Ph2PCH2OH[J].Journal of the Chemical Society,Dalton Transactions,2000:2771-2778.
[9] JACOBSON R A.SMART,SAINT and SHELXT L[CP/DK].Madison,USA:Bruker AXS Inc,1998.
[10] SHELDRICK G M.SHELXS 97 and SHELXL 97[CP/DK].GÖttingen,Germany:University of GÖttingen,1997.
[11] NI Qing-ling,JIANG Xuan-feng,HUANG Ting-hong,et al.Gold(Ⅰ) chloride complexes of polyphosphine ligands with electron-rich arene spacer:gold-arene interactions[J].Organometallics,2012,31(6):2343-2348.
[12] MANUEL B,ANTONIO L,VíCTOR M O,et al.Synthesis,structural characterization,and luminescence studies of gold(Ⅰ) and gold(Ⅲ) complexes with a triphosphine ligand[J].Inorganic Chemistry,1998,37(20):5125-5130.
[13] TZENG Biing-chiau,CHEN Bo-so,CHEN Chang-kai,et al.pH-dependent spectroscopic and luminescent properties,and metal-ion recognition studies of Re(Ⅰ) complexes containing 2-(2′-pyridyl)benzimidazole and 2-(2′-Pyridyl)benzimidazolate[J].Inorganic Chemistry,2011,50(12):5379-5388.
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