Journal of Guangxi Normal University(Natural Science Edition) ›› 2021, Vol. 39 ›› Issue (3): 92-101.doi: 10.16088/j.issn.1001-6600.2020030904

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Performance of Ru/ZrO2 Catalysts for Hydrogen Generation from Catalytic Hydrolysis of Ammonia Borane

SUN Haijie1, LIU Xingai1, CHEN Zhihao2*, CHEN Lingxia1*, ZHANG Lu1, MEI Yangyang1   

  1. 1. School of Chemistry and Chemical Engineering, Zhengzhou Normal University, Zhengzhou Henan 450044, China;
    2. Zhengzhou Tobacco Research Institute, China National Tobacco Corporation, Zhengzhou Henan 450001, China
  • Received:2020-03-09 Revised:2020-07-23 Published:2021-05-13

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Abstract: ZrO2 supported Ru catalysts were synthesized with an impregnation-chemical reduction method using NaBH4 as the reducing agent. The prepared catalysts were evaluated for the hydrogen generation via catalytic hydrolysis of BH3NH3. Effect of catalytic activity was investigated by varying the impregnated Ru loading, amount of reducing agent, reduction temperature as well as the reaction conditions. It was found that the TOF (Turnover Frequency) of 38.4 mol/mol(Ru)·min was achieved by adjusting Ru loading to 0.4 at 303 K of reaction temperature, while the molar ratio of Ru to NaBH4 was 1:1.6. The Ru particle size of 3.2 nm was observed. Moreover, when the stirring speed was 450 r/min, external diffusion could be eliminated, leading to the highest reaction rate towards hydrogen generation. In addition, catalytic activity increased with enhancing the amount of used catalyst, indicating that catalytic hydrolysis of BH3NH3 towards hydrogen production was controlled by the interfacial reaction over the catalyst surface. Furthermore, with the reaction temperature increasing, it gets more suitable for the desorption of NaBO2, the side product of hydrolysis of BH3NH3, from the catalyst surface. This results in the enhancement of the reaction rate towards hydrogen formation. According to the kinetic calculation, it suggests that the reaction rate of hydrolysis of BH3NH3 towards hydrogen generation over Ru/ZrO2 is irrelevant to the concentration of BH3NH3. The activation energy is 66 kJ/mol.

Key words: Ru, ZrO2, catalyst, ammonia borane, hydrogen generation

CLC Number: 

  • TQ116
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