广西师范大学学报（自然科学版） ›› 2022, Vol. 40 ›› Issue (5): 168-182.doi: 10.16088/j.issn.1001-6600.2022011804

• 综述 • 上一篇    下一篇

自由基稀土配合物:研究现状、挑战与展望

严海涵, 张文雄*   

  1. 北京大学 化学与分子工程学院, 北京 100871
  • 收稿日期:2022-01-18 修回日期:2022-04-11 出版日期:2022-09-25 发布日期:2022-10-18
  • 通讯作者: 张文雄(1972—), 男, 湖南宁乡人, 北京大学教授, 博导。 E-mail: wx_zhang@pku.edu.cn
  • 基金资助:
    国家杰出青年科学基金(21725201); 国家自然科学基金委重大项目(21890721); 国家重点研发计划(2021YFF0701600); 北京分子科学国家研究中心资助项目

Radical Rare-earth Metal Complexes: Advances, Challenges and Prospects

YAN Haihan, ZHANG Wenxiong*   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  • Received:2022-01-18 Revised:2022-04-11 Online:2022-09-25 Published:2022-10-18

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摘要： 自由基稀土配合物因其独特的化学反应活性和磁学性质,近30余年来一直受到许多课题组的重视。科学家们一直在尝试自由基配体、闭壳层配体和稀土金属间的不同组合,以调控自由基稀土配合物的不同性质。本文按照该领域历史的发展脉络,分中性自由基配体和自由基阴离子配体两部分综述现有自由基稀土配合物的常见结构、配体类型、配位模式,以及不同类型自由基稀土配合物的化学反应性和磁学性质,并对该领域的发展前景做出展望。

关键词: 稀土金属, 自由基, 配体, 配位化学, 配合物

Abstract: In the family of rare-earth metal complexes, radical rare-earth metal complexes have attracted great attention of the researchers in the past 30 years because of their unique chemical reactivities and magnetic properties. To fine-tune the different properties of radical rare-earth metal complexes, scientists have developed different combinations of radical ligands, closed-shell ligands and rare-earth metal centers. Herein, the reported structures, ligand types, coordination modes, chemical reactivity and magnetic properties of radical rare-earth metal complexes were reviewed according to the history of this field, and was divided into two parts as neutral/anionic radical ligands. The outlook of this field was also presented.

Key words: rare-earth metal, radical, ligand, coordination chemistry, complex

中图分类号: 

  • O614.33
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