Journal of Guangxi Normal University(Natural Science Edition) ›› 2013, Vol. 31 ›› Issue (2): 64-68.

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Synthesis and Optical Properties of 12-Aryl Substituted Derivatives of Methyl Dehydroabietate

HUA Shi-xian1, WANG Ying-chun2, LI Ya-jun1, WANG Heng-shan1   

  1. 1.College of Chemistry and Chemical Engineering,Guangxi NormalUniversity,Guilin Guangxi 541004,China;
    2.College of Chemistry and Chemical Engineering,Jishou University,Jishou Hunan 416000,China
  • Received:2013-02-01 Online:2013-06-20 Published:2018-11-26

Abstract: Starting from dehydroabietic acid which was purifieddisproportionated rosin,one important intermedia,methyl 12-bromo-13-nitro-7-oxo dehydrodeisopropylabietate (5) was synthesized through methylation,7-oxidation,12-bromination and 13-nitration.Then treatment of it with four kinds of arylboronic acids by palladium-catalyzed Suzuki cross-couplingreaction resulted in a series of 12-aryl substituted derivatives of methyl dehydroabietate.The structures of the compounds were characterized by IR,MS,1H NMRand 13C NMR.The opticalproperties of the products,such as theirultraviolet-visible spectrum and fluorescent spectrum were determined and studied.

Key words: dehydroabietic acid, arylboronic acids, Suzuki cross-coupling reaction, synthesis

CLC Number: 

  • O621.3
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