调控分子筛B酸和L酸比例用于催化糠醛高值转化

doi:10.16088/j.issn.1001-6600.2024091801

摘要/Abstract

摘要： γ-戊内酯和乙酰丙酸酯作为重要的生物质平台分子,在化学品、液体燃料和聚合物的生产中具有广阔应用前景。本文制备一种酸性可调控的P-Zr/H-Beta双功能催化剂,用于糠醛选择性转化制备γ-戊内酯和乙酰丙酸酯。该催化剂在异丙醇作为氢供体的条件下,可有效催化糠醛通过转移加氢、开环和环化反应等合成γ-戊内酯和乙酰丙酸酯。在150 ℃,γ-戊内酯和乙酰丙酸酯的收率分别为41.6%和23.7%,总收率为65.3%。糠醛转移加氢的活性取决于催化剂的酸碱性质,这与P-Zr/H-Beta中的P与Zr的物质的量之比密切相关。此外,本文还探讨时间、温度等反应参数对γ-戊内酯和乙酰丙酸酯收率的影响,并进一步对P-Zr/H-Beta的结构进行详细表征。

关键词: 糠醛, γ-戊内酯, 乙酰丙酸酯, 转移加氢, Beta分子筛

Abstract: As important biomass platform molecules, isopropyl levulinate and γ-valerolactone have promising applications in the production of chemicals, liquid fuels and polymerization. The acidity-tunable P-Zr/H-Beta bifunctional catalyst for the selective conversion of furfural to γ-valerolactone and isopropyl levulinate were prepared. The catalyst could effectively catalytic production of γ-valerolactone and isopropyl levulinate from furfural via transfer hydrogenation, ring opening and cyclization reactions with isopropanol as the hydrogen donor. The yields of γ-valerolactone and isopropyl levulinate were 41.6% and 23.7%, respectively, with a total yield of 65.3% at 150 ℃. The reaction activity of transfer hydrogenation mainly depended on the acid-base sites of catalyst, which was determined by the molar ratio of P to Zr in P-Zr/H-Beta. In addition, the effects of reaction parameters such as time and temperature on the yield of γ-valerolactone were explored; and the structure of P-Zr/H-Beta was further characterized in detail.

Key words: furfural, γ-valerolactone, isopropyl levulinate, transfer hydrogenation, Beta zeolite

中图分类号: O621;X703;TQ426

彭子芮, 姬为龙, 徐波, 宗艳龙, 乔学义, 芦天亮, 王剑峰. 调控分子筛B酸和L酸比例用于催化糠醛高值转化[J]. 广西师范大学学报（自然科学版）, 2025, 43(4): 175-187.

PENG Zirui, JI Weilong, XU Bo, ZONG Yanlong, QIAO Xueyi, LU Tianliang, WANG Jianfeng. Regulating the Ratio of B Acid and L Acid in Zeolites for High-Value Conversion of Furfural[J]. Journal of Guangxi Normal University(Natural Science Edition), 2025, 43(4): 175-187.

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