Journal of Guangxi Normal University(Natural Science Edition) ›› 2010, Vol. 28 ›› Issue (2): 69-73.

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Synthesis and Structure of a Novel Three-dimensional Zn2+Coordination Polymer with Topology (63.103)(63)

YIN Gang-qiang1,2, HUANG Huo-ming1, WANG Xiu-jian3   

  1. 1. School of Pharmacy,Guangdong Medical College,Zhanjiang Guangdong 524023,China;
    2. State Key Laboratory of Structural Chemistry,Fuzhou Fujian 350002,China;
    3. College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2010-03-25 Online:2010-06-20 Published:2023-02-07

Abstract: A three-dimensional Zn2+ coordination polymer[Zn2(SSS)2(bipy)]n was prepared under hydrothermal method with 4,4'-bipyridine (bipy) and tridentate 1,3,4-thiadiazole-2,5-disulfide (SSS2-) as ligands and characterized by elemental analysis,IR spectrum and TG.Its structure was determined by single-crystal X-ray diffraction.In the title complex,each SSS2- anion links three Zn2+ ions while each Zn2+ links three SSS2- anions,constructing a two-dimensional plane which is parallel to the ab plane.Neighboring 2-D planes are interlinked by bridging 4,4'-bipyridine molecules,resulting in a novel 3D polymeric architecture.This 3D architecture represents a new topology with schlafli symbol (63.103)(63).The title complex shows high thermal stability (up to 350 °C).

Key words: zinc complex, coordination polymer, topology, thermal stability

CLC Number: 

  • O641.4
[1] HORIKE S,SHIMOMURA S,KITAGAWA S.Soft porous crystals[J].Nature Chem,2009,1:695-704.
[2] TRANCHEMONTAGNE D J,MENDOZA-CORTES J L,O'KEEFFE M,et al.Secondarybuilding units,nets and bonding in the chemistry of metal-organic frameworks[J].Chem Soc Rev,2009,38:1257-1283.
[3] LEE S J,LIN Wen-bin.Chiral metallocycles:Rational synthesis and novel applications[J].Accounts Chem Res,2008,41:521-537.
[4] JANIAK C.Engineering coordination polymers towards applications[J].Dalton Trans,2003:2781-2804.
[5] HONG Mao-chun.Inorganic-organic hybrid coordination polymers:A new frontier for materials research[J].Cryst Growth Des,2007,7:10-14.
[6] LI Zhi-hua,DU Shao-wu,WU Xin-tao.Assembly of molecular squaresand helical chain polymers of Mo(W)/Cu/S clusters using thiolato ligands as linkers[J].Polyhedron,2005,24:2988-2993.
[7] LI Zhi-hua,LIN Ping,DU Shao-wu.Syntheses and characterization ofthree novel W(Mo)/Cu/S cluster-based layered polymers with 1,3,4-thiadiazole-2,5-dithiolate (SSS):Intriguing coordination modes of SSS[J].Polyhedron,2008,27:232-240.
[8] MA Chun-lin,LI Feng,JIANG Qin,et al.Syntheses and crystal structures of di- and triorganotin derivatives with 2,5-dimercapto-1,3,4-thiodiazole[J].J Organomet Chem,2004,689:96-104.
[9] TANNAI H,TSUGE K,SASAKI Y,et al.Oyama,monodentate and bridging coordination of 2,5-dimercapto-1,3,4-thiadiazolate to a (2,2′:6′,2″-terpyridine)platinum(Ⅱ) center[J].Dalton Trans,2003:2353-2358.
[10] TZENG Biing-chiau,WU Ya-ling,LEE Gene-hsiang,et al.A novel trinuclear Re(Ⅰ) complex containing 1,3,4-thiadiazole-2,5-dithiolate:structuraland spectroscopic properties[J].New J Chem,2007,31:199-201.
[11] TANNAI H,TSUGE K,SASAKI Y.Switching of the electronic communication between two {Ru(trpy)(bpy)} (trpy=2,2′:6′,2″-terpyridine and bpy=2,2′-bipyridine) centers by protonation on the bridging dimercaptothiadiazolato ligand[J].Inorg Chem,2005,44:5206-5208.
[12] KONDO A,NOGUCHI H,CARLUCCI L,et al.Double-step gas sorption of atwo-dimensional metal-organic framework[J].J Am Chem Soc,2007,129:12362-12363.
[13] BARNETT S A,CHAMPNESS N R.Structural diversity of building-blocks in coordination framework synthesis—combining M(NO3)2 junctions and bipyridyl ligands[J].Coord Chem Rev,2003,246:145-168.
[14] WARD M D.[Ru(bipy)(CN)4]2 and its derivatives:Photophysicalproperties and its use in photoactive supramolecular assemblies[J].Coord ChemRev,2006,250:3128-3141.
[15] SHELDRICK G M.SHELXS97,Program for X-ray crystal structure solution[CP/CD].Go¨ttingen,Germany:University of Go¨ttingen,1997.
[16] SHELDRICK G M.SHELXL97,Program for X-ray crystal structure refinement[CP/CD].Go¨ttingen,Germany:University of Go¨ttingen,1997.
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