Journal of Guangxi Normal University(Natural Science Edition) ›› 2010, Vol. 28 ›› Issue (2): 69-73.

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Synthesis and Structure of a Novel Three-dimensional Zn2+Coordination Polymer with Topology (63.103)(63)

YIN Gang-qiang1,2, HUANG Huo-ming1, WANG Xiu-jian3   

  1. 1. School of Pharmacy,Guangdong Medical College,Zhanjiang Guangdong 524023,China;
    2. State Key Laboratory of Structural Chemistry,Fuzhou Fujian 350002,China;
    3. College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2010-03-25 Online:2010-06-20 Published:2023-02-07

Abstract: A three-dimensional Zn2+ coordination polymer[Zn2(SSS)2(bipy)]n was prepared under hydrothermal method with 4,4'-bipyridine (bipy) and tridentate 1,3,4-thiadiazole-2,5-disulfide (SSS2-) as ligands and characterized by elemental analysis,IR spectrum and TG.Its structure was determined by single-crystal X-ray diffraction.In the title complex,each SSS2- anion links three Zn2+ ions while each Zn2+ links three SSS2- anions,constructing a two-dimensional plane which is parallel to the ab plane.Neighboring 2-D planes are interlinked by bridging 4,4'-bipyridine molecules,resulting in a novel 3D polymeric architecture.This 3D architecture represents a new topology with schlafli symbol (63.103)(63).The title complex shows high thermal stability (up to 350 °C).

Key words: zinc complex, coordination polymer, topology, thermal stability

CLC Number: 

  • O641.4
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