Journal of Guangxi Normal University(Natural Science Edition) ›› 2020, Vol. 38 ›› Issue (4): 92-99.doi: 10.16088/j.issn.1001-6600.2020.04.011

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Synthesis, Characterization and Crystal Structures of Complexes ContainingOrganic Phosphine Gold Acetylene and Triazoles

XIE Tingting, XIE Yao, NI Qingling*   

  1. School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin Guangxi 541004, China
  • Received:2019-07-25 Published:2020-07-13

Abstract: Reaction of two new phosphine ligands, N, N′-bis [(diphenylphosphine) methylene]-N, N′-bis(4-pyridine methyl)-p-phenylenediamine (L1) and N, N′-bis[(diphenylphosphine) methylene]-N, N′-bis(2-pyridine methyl)-p-naphthalene diamine (L2), with gold salts [AuCl(THF)] (THF = tetrahydrofuran) produced organic phosphine gold chloride complexes. Then, it generated organic phosphonic alkyne complexes of gold by further treatment with phenylacetylene. The obtained gold alkyne complexes reacted with trimethylsilane azide to generate 1, 2, 3-triazoles complexes. These complexes were characterized by infrared spectrum, nuclear magnetic spectrum and X-ray single crystal diffraction. It was found that the weak Au-π interactions play a certain role in the stability of the complexes.

Key words: phosphine ligand, phosphine-gold complexes, synthesis, crystal structures, Au-π interactions

CLC Number: 

  • O641
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