Journal of Guangxi Normal University(Natural Science Edition) ›› 2012, Vol. 30 ›› Issue (1): 55-59.

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Synthesis and Property of Dehydroabieticacyl Diamino Surfactants

YANG Da, SU Chun-hua, ZHAO Zhi-cai, TIAN Xiao-yan, PAN Ying-ming, WANG Heng-shan   

  1. State Key Laboratory Cultivation Base for the Chemistry and Molecular Engineering of Medicinal Resources,College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2011-09-20 Online:2012-01-20 Published:2018-12-03

Abstract: Five dehydroabieticacyl diamino chiral surfactants,including four betaines-typed zwitterionic surfactants 4a~4d and one anionic chiral surfactants 3c wereprepared from dehydroabietic acid (DHAA) in medium to high yields,through short-steps and simplified post-processing procedures.The conditions for purification of the title compounds by crystallization were proposed.In addition,some of their surface properties such as the critical micelle concentration (CMC),the values of surface tension at the CMC (γcmc),emulsification capacity andfoaming capacity of all the target compounds were characterized and compared.Compound 4c have good emulsification capacity among allthe derivatives.The attitude of 4c deserve specialconsideration for the application in chiral separation.

Key words: chiral surfactant, synthesis, rosin acid, surface active properties

CLC Number: 

  • O623.62
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