Journal of Guangxi Normal University(Natural Science Edition) ›› 2013, Vol. 31 ›› Issue (4): 98-102.

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A Simple and Sensitive Fluorescence Method for Determination of Trace O3 in Air Using Rhodamine 6G

LIANG Ai-hui, YANG Duo, LIN Chen-yin, WEN Gui-qing   

  1. College of Environment and Resource,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2013-06-15 Online:2013-12-20 Published:2018-11-26

Abstract: Ozone (O3) reacted with KI-H3BO3 absorption liquid to produce iodine (I2),when the I- excessive,it form I-3.In the pH4.0 HAc-NaAc (1.67 mmol/L) buffer solution,I-3 and RhG form RhG-I3 ion association particles that resulted in the resonance of the fluorescence peak decreases at 556 nm.The decreased value ΔF556 nm is linear to the I2 concentration in the range of 0.97~15.4 μmol/L.And the concentration of I2 is equivalent to O3,with a regression equation of ΔF556 nm=274.94C+52.03,coefficient of 0.991 8 and a detection limit of 0.5 μmol/L.This method was applied to determination of ozone in air sample,and its results were agreement with that of spectrophotometry.

Key words: ozone, rhodamin 6G, associated particle, fluorescence method

CLC Number: 

  • O657
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