Journal of Guangxi Normal University(Natural Science Edition) ›› 2012, Vol. 30 ›› Issue (1): 67-70.

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Synthesis and Structure of (Pyrazin-2-ylsulfanyl)-Acetic Acid

MENG Xiu-jin, YANG Da, JIANG Yi-min   

  1. State Key Laboratory Cultivation Base for the Chemistry and Molecular Engineering of Medicinal Resources,College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2011-11-03 Online:2012-01-20 Published:2018-12-03

Abstract: 2-Mercaptopyrazine (1) was synthesized from 2-chloropyrizine and sulfourea,(pyrazin-2-ylsulfanyl)-acetic acid was synthesized from 2-mercaptopyrazine and chloroacetic acid.The structures ofcompounds 1,2 were analyzed by IR、MS and X-ray single-crystal diffraction analyses.

Key words: 2-chloropyrizine, 2-mercaptopyrazine, (pyrazin-2-ylsulfanyl)-acetic acid, synthesize

CLC Number: 

  • O629.72
[1] HU Sheng,HE Kun-huan,ZENG Ming-hua,et al.Crystalline-state guest-exchange and gas-adsorption phenomenon for a “soft” supramolecular porousframework stacking by a rigid linear coordination polymer[J].Inorg Chem,2008,47:5218-5224.
[2] HUANG Fu-ping,LI Hai-ye,TIAN Jin-lei,et al.A three-dimensional(42.84)-lvt topology and a two dimensional brick-wall network:two pillared supramolecular isomers exploring the use of L-cysteic acid to engineer porous frameworks[J].Crystal Growth and Design,2009,9(7):3191-3196.
[3] 黄廷洪,王苗,马凯,等.[Ag(pba)(Et-dtc)]·p-C6H4(CH3)2配合物的合成、晶体结构及光谱性质[J].广西师范大学学报:自然科学版,2011,29(3):43-46.
[4] 蒋毅民,谭黎峰,闭献树.希夫碱2,6-双(1-苯基亚氨基甲基)吡啶的合成及晶体结构[J].广西师范大学学报:自然科学版,2000,18(3):68-70.
[5] ZHANG Shu-hua,LI Ning,GE Cheng-min,et al.Structures and magnetism of {Ni2Na2},{Ni4} and {NiII6NiIII} 2-hydroxy-3-alkoxy-benzal-dehyde clusters[J].Dalton Transactions,2011,40:3000-3007.
[6] 徐虹,张宇虹,谢少培,等.二维配位聚合物{[Cd(btmb)(1,4-bdc)2·H2O·CH3OH]}n的合成、结构和荧光性质[J].郑州大学学报:理学版,2010,42(2):104-106.
[7] 肖晴,林展如.咪唑型金属配合物的合成和性能研究[J].四川师范大学学报:自然科学版,1998,21(4):436-440.
[8] XIAO Yu,ZHANG Shu-hua,LI Guang-zhao,et al.Synthesis,crystal structure and magnetic properties of cubane and linear trinuclear nickel complexes formed by 3,5-dichloro-2-hydroxybenzylaminoacetic acid[J].Inorg Chim Acta,2011,366:39-43.
[9] GE Cheng-min,ZHANG Shu-hua,FENG Chao,et al.Heterotetranuclear metal complex {Ni2Na2} architecture by azido-bridged[J].Z Anorg Allg Chem,2011,637:112-116.
[10] ZOU Hua-hong,ZHANG Shu-hua,XIAO Yu,et al.Solvothermal synthesisand structures of three novel heterometa-llic microporous coordination polymersassembled from 2-hydroxy-nicotinic acid[J].Struct Chem,2011,22:135-140.
[11] ZOU Hua-hong,HE Yan-ping,GUI Liu-cheng,et al.A new 8-connectedporous coordination polymer:crystal structure and selective adsorption properties[J].Cryst Eng Comm,2011,13:3325-3329.
[12] ZHANG Shu-hua,MA Lu-fang,ZOU Hua-hong,et al.Anion induced diversification from heptanuclear to tetranuclear clusters:syntheses,structures andmagnetic properties[J].Dalton Trans,2011,40:11402-11409.
[13] 倪青玲,陶杰,石敏,等.1-(吡啶-3-甲基)-2-乙基苯并咪唑的合成及抑菌活性[J].广西师范大学学报:自然科学版,2009,27(2):72-75.
[14] 陈煦,李永强,张和,等.2-巯基吡啶的合成及结构测定[J].天津化工,2000,5:26-27.
[15] 赵海涛,刘双培,郭栋材.2-巯基苯并噻唑羧酸衍生物的润滑性[J].湖南大学学报:自然科学版,1998,125(4):33-35.
[16] 杨爱红,房素荣,张燕平,等.吡嗪-2,3,5,6-四甲酸镍配合物[Ni(ptcH2)(bpy)(H2O)]的水热合成、结构及性质[J].无机化学学报,2008,24(3):487-490.
[17] 张华.现代有机波谱分析[M].北京:化学工业出版社,2005:267-295.
[18] SHELDRICK G M.SHELXS-97,program for the solution of crystalstructures[CP/CD].Gottingen:University of Gottingen,1997.
[19] SHELDRICK G M.SHELXL-97,program for the refinement of crystalstructures[CP/CD].Gottingen:University of Gottingen,1997.
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