广西师范大学学报（自然科学版） ›› 2013, Vol. 31 ›› Issue (2): 69-75.

• • 上一篇    下一篇

氢键导向的三维超分子结构{[Co(4,4'-bipy)(H2O)4](pda)2(H2O)2}n的合成及晶体结构(pda-=2-甲基苯并咪唑-1,3-二乙酸根)

曾建强, 梁光明, 黄瑛达, 杨坤国, 桂柳成, 倪青玲   

  1. 广西师范大学化学化工学院,广西桂林541004
  • 收稿日期:2012-12-09 出版日期:2013-06-20 发布日期:2018-11-26
  • 通讯作者: 倪青玲(1964—),女,广西全州人,广西师范大学副教授。E-mail:niql123@sina.com
  • 基金资助:
    国家自然科学基金资助项目(21202024,21201045);广西自然科学基金资助项目(2010GXNSFF013001)

Hydrogen-bonding Directed Three-dimensional Supramolecular Structure in Catena-((μ2-4,4'-bipyridine)-tetraaqua-cobalt(Ⅱ) bis (2-methylbenzimidazolium-1,3-diacetate) dehydrate): Synthesis and Crystal Structural Characterization

ZENG Jian-qiang, LIANG Guang-ming, HUANG Ying-da, YANG Kun-guo, GUI Liu-cheng, NI Qing-ling   

  1. College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China
  • Received:2012-12-09 Online:2013-06-20 Published:2018-11-26

摘要： 标题化合物{[Co(4,4'-bipy)(H2O)4](pda)2(H2O)2}n由醋酸钴、3-羧甲基-1,3-(2-甲基苯并咪唑基)-1-乙酸(Hpda)和4,4'-联吡啶通过水热反应而得。X射线单晶衍射分析显示该化合物的不对称单元含有半个Co2+离子、半个4,4'-联吡啶分子、1个抗衡阴离子pda-、2个配位水分子和1个结晶水分子。标题配合物中Co2+被4,4'-联吡啶分子桥联形成一维链{[Co(4,4'-bipy)]}n,同时4个配位水分子和来自不同4,4'-联吡啶分子中的2个氮原子与Co2+配位形成六配位的八面体结构。在固态结构里,抗衡阴离子pda-、配位水和结晶水分子通过O—H…O氢键作用构筑形成二维波浪形状的氢键结构,同时相邻二维氢键层被4,4'-联吡啶分子进一步以柱状连接形成拥有一维通道的三维超分子结构。

关键词: 配位聚合物, 超分子, 氢键, 晶体结构

Abstract: The title compound,{[Co(4,4'-bipy)(H2O)4](pda)2(H2O)2}n,was obtained by the hydrothermal reaction of cobalt acetate with 3-carboxymethyl-1,3-(2-methylbenzimidazolium)-1-acetate (Hpda) and4,4'-bipyridine (4,4'-bipy).X-ray single crystal diffraction shows that the asymmetric unit of the title compound contains half a Co2+ ion,half a 4,4'-bipy molecule,one counter anion pda-,two coordinated water molecules andone lattice water molecule.Co2+ ions are bridged by 4,4'-bipy moleculesresulting in a one-dimensional coordination chain,{[Co(4,4'-bipy)(H2O)4]2+}n,in which Co2+ center is six-coordinated by two nitrogen atoms from different 4,4'-bipy molecules and four oxygen atoms from coordinated water molecules.In the solid state,two-dimensional undulating layers are constructed through hydrogen bonds between pda- anions,coordinated water and crystallization water molecules,while neighboring hydrogen-bonding layers are further pillared by 4,4'-bipy into a three-dimensional supramolecular structure which contains one-dimensional channels.

Key words: coordination polymer, supramolecule, hydrogen bond, crystal structure

中图分类号: 

  • O641.4
[1] HAN Zheng-bo,JI Jian-wei,AN Hai-yan,et al.Two 3D chiral coordination polymers with 4-connected 66 topological net:synthesis,structure and magnetic properties[J].Dalton Trans,2009:9807-9811.
[2] BIRADHA K,SU Cheng-yong,VITTAL J J.Recent developments in crystalengineering[J].Cryst Growth & Des,2011,11(4):875-886.
[3] NI Qing-ling,JIANG Xuan-feng,GUI Liu-cheng,et al.Synthesis,structures and characterization of a series of Cu(Ⅰ)-diimine complexes with labile N,N'-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine:diverse structures directed by π-π stacking interactions[J].New J Chem,2011,35:2471-2476.
[4] WANG Xiu-jian,GUI Liu-cheng,NI Qing-ling,et al.π-Stacking induced complexes with Z-shape motifs featuring a complementary approachbetween electron-rich arene diamines and electron-deficient aromatic N-heterocycles[J].Cryst Eng Comm,2008,10:1003-1010.
[5] HOU Ruo-bing,HUANG Ting-hong,WANG Xiu-jian,et al.Synthesis,structural characterization and luminescent properties of a series of Cu(Ⅰ) complexes based on polyphosphineligands[J].Dalton Trans,2011,40:7551-7558.
[6] HU Fei-long,YIN Xian-hong,MI Yan,et al.Synthesis,structure and properties of a new copper(Ⅱ) complex,[Cu2(4,4'-bpy)5(H2O)4](ClO4)4-(4,4'-bpy)(DMF)2(H2O)2[J].Inorg Chem Commun,2010,13(6):720-723.
[7] HU Fei-long,YIN Xian-hong,LU Jie,et al.Crystal structure,bioactivities,and electrochemistry properties of four diverse complexes with a new pyrazole ligand[J].J Coord Chem,2010,63(2):263-272.
[8] MIN K S,SUH M P.Silver(Ⅰ)-polynitrile network solids for anion exchange:anion-induced transformation of supramolecular structure in the crystalline state[J].J Am Chem Soc,2000,122(29):6834-6840.
[9] YAGHI O M,LI Hai-lian,DAVIS C,et al.Synthetic strategies,structure patterns,and emerging properties in the chemistry of modular porous solids[J].Acc Chem Res,1998,31(8):474-484.
[10] ALLEN F H.The cambridge structural database:a quarter of a million crystal structures and rising[J].Acta Crystallogr Sect B:Struct Sci,2002,B58:380-388.
[11] WANG Xiu-jian,JIAN Hong-xia,LIU Zi-ping,et al.Assembly molecular architectures based on structural variation of metalloligand [Cu(PySal)2](PySal=3-pyridylmethylsalicylideneimino)[J].Polyhedron,2008,27(12):2634-2642.
[12] MA Lu-fang,LI Cheng-peng,WANG Li-ya,et al.Co(Ⅱ) and Zn(Ⅱ) coordination frameworks with benzene-1,2,3-tricarboxylate tecton and flexible dipyridyl Co-ligand:a new type of entangled architecture and a unique 4-connected topological network[J].Cryst Growth & Des,2011,11(8):3309-3312.
[13] YU Pei,KAHN O,NAKATANI K,et al.Design of a molecular-based ferromagnet through polymerization reaction in the solid state of manganese(Ⅱ) copper(Ⅱ) molecular units.Crystal structure of MnCu(obze)(H2O)4·2H2O(obze=oxamido-N-benzoato-N'-ethanoato)[J].J Am Chem Soc,1991,113(17):6558-6564.
[14] XU Yun,LUO Feng,CHE Yun-xia,et al.A new eight-connected net with CsCl-type topology built on unique [Co2(μ3-OH)(μ2-OH)2(CO2)3]2 building blocks[J].Inorg Chem Commun,2009,12(7):639-641.
[15] GHOSH S,BAG P P,REDDY C M.Co-Crystals of sulfamethazine with some carboxylic acids and amides:Co-former assisted tautomerism in an active pharmaceutical ingredient and hydrogen bond competition study[J].Cryst Growth & Des,2011,11(8):3489-3503.
[16] 邱志惠,梁福沛,阮青锋.[Cu(C8H6NO2)2(H2O)2]n的水热合成和晶体结构[J].广西师范大学学报:自然科学版,2008,26(3):53-56.
[17] 宋丽华,金一,梁福沛.含氮多羧酸钴(Ⅱ)-钕(Ⅲ)异核配合物合成和晶体结构[J].广西师范大学学报:自然科学版,2012,30(2):106-110.
[18] 吴旭先,雷超海,秦愫妮,等.[VO2(C12H7N2O4)H2O]的合成与晶体结构[J].广西师范大学学报:自然科学版,2009,27(3):40-44.
[19] ADDISON A W,RAO T N,REEDIJK J,et al.Synthesis,structure,and spectroscopic properties of copper(Ⅱ) compounds containing nitrogen-sulphur donor ligands;the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2-yl)-2,6-dithiaheptane] copper(Ⅱ) perchlorate[J].J Chem Soc Dalton Trans,1984:1349-1356.
[20] WANG Xiu-jian,CEN Zhong-min,NI Qing-ling,et al.Synthesis structures,and properties of functional 2-D lanthanide coordination polymers [Ln2(dpa)2(C2O4)2(H2O)2]n (dpa=2,2'-(2-methylbenzimidazolium-1,3-diyl)diacetate,C2O2-4=oxalate,Ln=Nd,Eu,Gd,Tb)[J].Cryst Growth &Des,2011,10(7):2960-2968.
[21] NI Qing-ling,LI Fa-si,JIN Ling-ling,et al.Synthesis and crystal structure of N,N'-dicarboxymethyl-2-methylbenzimidazole[J].Chem Res Appl,2007,19:1181-1184.
[22] BRUKER.SMART,SAINT and SADABS[CP/CD].Madison,USA:Bruker AXS Inc,1998.
[23] SHELDRICK G M.SHELXS97 and SHELXL97[CP/CD].Göttingen,Germany:University of Göttingen,1997.
[24] SHELDRICK G M.SHELXTL97[CP/CD].Göttingen,Germany:University of Göttingen,1997.
[25] JACOBSON R.REQAB[CP/CD].Woodlands,USA:Molecular Structure Corporation,1998.
[26] WEI Guo-hua,JIN Yang,MA Jian-fang,et al.Synthesis,structures and luminescent properties of zinc(Ⅱ) and cadmium(Ⅱ) coordination complexes based on new bis(imidazolyl)ether and different carboxylate ligands[J].Dalton Trans,2008:3080-3092.
[1] 谢婷婷, 谢瑶, 倪青玲. 含有机膦金炔三氮唑配合物的合成表征及晶体结构[J]. 广西师范大学学报（自然科学版）, 2020, 38(4): 92-99.
[2] 黄学仁, 赵志愿, 蒋毅民. 4′-(4-苯甲酸)-2,2′:6′,2″-三联吡啶锌配位聚合物的合成、晶体结构及荧光性质研究[J]. 广西师范大学学报（自然科学版）, 2016, 34(2): 98-104.
[3] 王亚娜, 林家皇, 倪青玲, 张芳, 余荣华, 王修建. 2-[1,3-二(2-羟基苯甲基)-5-吡啶基-4-咪唑烷基]苯酚的合成及晶体结构[J]. 广西师范大学学报（自然科学版）, 2016, 34(2): 105-110.
[4] 刘汉甫, 马献力, 陈素一, 沈雪松, 黄富平. 锌三元配合物的合成及其抑菌活性研究[J]. 广西师范大学学报（自然科学版）, 2015, 33(4): 103-107.
[5] 梁晓龙, 黄婉云, 潘成学, 苏桂发. 5-乙酰胺基-4-(4-氯苯基)-2-甲基-6-氧代-5, 6-二氢-4H-吡喃-3-羧酸乙酯的合成及晶体结构[J]. 广西师范大学学报（自然科学版）, 2015, 33(2): 82-87.
[6] 蒋丽萍, 黄婉云, 刘冬成, 梁福沛. 水杨醛联二萘酚二甲酰腙Zn(Ⅱ)、Cu(Ⅱ)配合物的合成及晶体结构[J]. 广西师范大学学报（自然科学版）, 2015, 33(1): 93-98.
[7] 霍红月, 李仲庆, 覃其品, 刘延成, 陈振锋. 邻香草醛缩胡椒乙胺席夫碱锌(Ⅱ)配合物的研究[J]. 广西师范大学学报（自然科学版）, 2014, 32(3): 65-73.
[8] 吴睿, 张楠曦, 张潇. 拟卤素化合物Cu[N(CH2OH)2CH2O](SCN)的合成、晶体结构和磁性[J]. 广西师范大学学报（自然科学版）, 2013, 31(4): 78-83.
[9] 陈思园, 杨扬, 彭艳, 刘延成. 一种新型希夫碱钯配合物的晶体结构及抗肿瘤活性研究[J]. 广西师范大学学报（自然科学版）, 2013, 31(2): 81-86.
[10] 张中, 胡坤, 林信良, 孙迎迎. 2-[2-(1H-1,2,4-三氮唑-1-基)乙基]-1H-苯并咪唑水合物的合成、晶体结构及光谱研究[J]. 广西师范大学学报（自然科学版）, 2013, 31(1): 57-61.
[11] 李海叶, 蒋毅民, 蒙秀金. 邻菲咯啉-磺基丙氨酸钴(Ⅱ)配合物的合成与晶体结构[J]. 广西师范大学学报（自然科学版）, 2013, 31(1): 72-75.
[12] 王修建, 丛新宇, 蒋选丰, 马凯, 张子豪, 曾建强, 倪青玲. 由Au…Au键诱导的Au-有机膦一维配位聚合物的合成、结构及表征[J]. 广西师范大学学报（自然科学版）, 2012, 30(3): 189-193.
[13] 张刘生, 潘成学, 李丽, 苏桂发, 黄婉云, 覃江克, 唐煌. 含环丙烷氨基酸残基的构象限制二肽的合成及其晶体结构研究[J]. 广西师范大学学报（自然科学版）, 2011, 29(3): 37-42.
[14] 黄婉云, 苏桂发, 潘成学, 覃江克, 唐煌, 义祥辉. 构象限制二肽的合成及其晶体结构研究[J]. 广西师范大学学报（自然科学版）, 2011, 29(2): 56-60.
[15] 尚静, 倪青玲, 桂柳成, 王修建, 黄廷洪, 马凯, 曾建强. 一维配位聚合物｛HgBr2[μ2-Cu(C26H22O2N4)]｝n的合成与晶体结构[J]. 广西师范大学学报（自然科学版）, 2011, 29(2): 61-64.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
版权所有 © 广西师范大学学报（自然科学版）编辑部
地址：广西桂林市三里店育才路15号　邮编：541004
电话：0773-5857325　E-mail: gxsdzkb@mailbox.gxnu.edu.cn
本系统由北京玛格泰克科技发展有限公司设计开发