镨离子掺杂钨酸铅晶体荧光衰减动态研究

广西师范大学学报（自然科学版） ›› 2011, Vol. 29 ›› Issue (2): 71-75.

镨离子掺杂钨酸铅晶体荧光衰减动态研究

熊飞兵^1,2, 杨峰³

1.中国科学院福建物质结构研究所,福建福州350002;
2.厦门理工学院数理系,福建厦门361024;
3.广西师范大学化学化工学院,广西桂林541004

收稿日期:2011-01-16 发布日期:2018-11-19
通讯作者: 熊飞兵(1976—),男,江西丰城人,厦门理工学院讲师,博士。E-mail:fbxiong@yahoo.com.cn
基金资助:
国家自然科学基金资助项目(C050102);福建省自然科学基金资助项目(2010J05014);福建省教育厅A类科技项目(JA10254);厦门市科技计划指导性项目(3502720099006)

Fluorescence Decay Dynamics of Praseodymium Ions Doped in Lead Tungstate Crystal

XIONG Fei-bing^1,2, YANG Feng³

1.Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou Fujian 350002,China;
2.Department of Physics and Mathematics,Xiamen University of Technology,Xiamen Fujian 361024,China;
3.College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin Guangxi 541004,China

Received:2011-01-16 Published:2018-11-19

摘要/Abstract

摘要： 测量Pr³⁺:PbWO₄晶体³P₀和¹D₂能级在常温下的荧光衰减曲线,计算这2个能级的荧光寿命。结合改进的Judd-Ofelt理论得到³P₀和¹D₂能级的辐射寿命,详细分析了这2个能级的荧光衰减动态情况。对于³P₀能级,其荧光衰减主要是受到多声子无辐射跃迁的影响;对于¹D₂能级,其无辐射衰减的主要通道是共振交叉能量传递。采用Inokuti-Hirayama模型,详细分析¹D₂能级的荧光衰减过程,证实其荧光猝灭机制是电偶极-电偶极交叉能量传递。

关键词: 荧光衰减动态, 镨离子掺杂钨酸铅晶体, 无辐射跃迁

Abstract: Fluorescence decay curves of the ³P₀ and¹D₂ manifolds in Pr³⁺ doped PbWO₄ crystal were measured at room temperature and fluorescence lifetimes of both manifolds were estimated.Combining with the radiative lifetimes of those manifolds calculated on the basis ofthe modified J-O theory,the fluorescence decay dynamics of those manifolds were analyzed.The multi-phonon relaxation and the cross-relaxation energy transfer are the major nonradiative relaxation for the excited ³P₀ and ¹D₂ manifolds,respectively.The Inokuti-Hirayama model was used to analyze the fluorescence decay curve of the ¹D₂ manifold and the cross-relaxation of dipole-dipole interaction was confirmed.

Key words: fluorescence decay dynamics, Pr³⁺-doped PbWO₄, non-radiative relaxation

中图分类号:

O433.1

熊飞兵, 杨峰. 镨离子掺杂钨酸铅晶体荧光衰减动态研究[J]. 广西师范大学学报（自然科学版）, 2011, 29(2): 71-75.

XIONG Fei-bing, YANG Feng. Fluorescence Decay Dynamics of Praseodymium Ions Doped in Lead Tungstate Crystal[J]. Journal of Guangxi Normal University(Natural Science Edition), 2011, 29(2): 71-75.

参考文献

[1] FIBRICH M,JELINKOVA H,SULC J,et al.Pr:YalO₃ microchip laser[J].Opt Lett,2010,35:2556-2557.
[2] NICOLAS S,DESCROIX E,JOUBERT M F,et al.Potentiality of Pr³⁺-and Ce³⁺ Pr³⁺-codoped crystals for tunable UV upconversion lasers[J].Opt Mater,2003,22:139-142.
[3] OKAMOTO H,KASUGA K,HARA L,et al.Visible-NIR tunable Pr³⁺-doped fiber laser pumped by GaN laser didode[J].Opt Exp,2009,17:20227-20232.
[4] TER-GABRIELYAN N,AANAMYAN T,DUBINSKII M.Resonantly pumped Pr³⁺-doped eye-safe laser at similar to 1.65 μm[J].Opt Lett,2009,34:1949-1951.
[5] XIONG Fei-bing,LIN Yan-fu,CHEN Yu-jin,et al.Visible quantum cutting in Pr³⁺:PWO₄ crystal through energy transfer between the host and Pr³⁺ ions[J].Chem Phys Lett,2006,429:410-414.
[6] HUANG Yuan-ling,TSUBOI T,SEO H J.Spectroscopic properties of Pr³⁺ ions in a PWO₄ signal crystal[J].J Phys Chem A,2008,112:5839-5845.
[7] CHEN Wei,INAGAWA Y,OMATSU T,et al.Diode-pumped,self-stimulating,passively Q-switched Nd³⁺:PbWO₄ Raman laser[J].Opt Comm,2001,194:401-407.
[8] XIONG Fei-bing,LUO Zun-du,HUANG Yi-dong.Spectroscopic properties of Pr³⁺ ions in anisotropic PWO₄ crystal[J].Appl Phys B:Laser Opt,2005,80:321-328.
[9] WEBER M J.Luminescence decays by energy migration and transfer:observation of diffusion-limited relaxation[J].Phys Rev B,1971,4:2932-2937.
[10] BLUMBERG W E.Nuclear spin-lattice relaxation caused by paramagnetic impurities[J].Phys Rev,1960,119:79-84.
[11] HUANG Yuan-ling,FENG Xi-qi,XU Zhu,et al.Growth and spectra properties of Nd³⁺ in anisotropic PbWO₄ crystal[J].Solid State Commun,2003,127:1-5.
[12] JUDD B R.Optical absorption intensities of rare-earth ions[J].Phys Rev,1962,127:750-756.
[13] OFELT G S.Intensities crystal spectra of rare-earth ions[J].J Chem Phys,1962,37:511-516.
[14] DUNINA E B,KAMINSKII A A,KORNIENKO A A,et al.The dependence of the line strength of electric dipole f-f transition on the manifold energy of thePr³⁺ ion in YAlO₃[J].Sov Phys Solid State,1990,32:290-295.
[15] MACALIK L,HANUZA J,KAMINSKII A A.Polarized Raman spectra of the oriented NaY(WO₄)₂ and KY(WO₄)₂ single crystals[J].J Mol Struct,2000,555:289-297.
[16] INOKUTI M,HIRAYAMA F.Intensity of energy transfer by exchanger mechanism on donor luminescence[J].J Chem Phys,1965,43:1978-1981.
[17] HAN Bao-guo,FENG Xi-qi,HU Guo-qiang,et al.Observation of dipole complexes in PbWO₄:La³⁺ single crystal[J].J Appl Phys,1998,84:2831-2835.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed