广西师范大学学报(自然科学版) ›› 2011, Vol. 29 ›› Issue (2): 65-70.

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表面化学法改性醋酸纤维素微滤膜

邱建华1,2, 张延武2, 张亚涛2, 张浩勤2, 刘金盾2   

  1. 1.广西师范大学化学化工学院,广西桂林541004;
    2.郑州大学化工与能源学院,河南郑州450001
  • 收稿日期:2010-10-31 发布日期:2018-11-19
  • 通讯作者: 邱建华(1979—),男,广西桂林人,广西师范大学讲师,博士。E-mail:qiujianhua@mailbox.gxnu.edu.cn
  • 基金资助:
    国家“863”项目(2008AA06Z330);国家自然科学基金资助项目(20676125)

Modification of Microporous Cellulose Acetate Membrane with Anionic Polyacrylamide by Chemical Surface-grafted Method

QIU Jian-hua1,2, ZHANG Yan-wu2, ZHANG Ya-tao2, ZHANG Hao-qin2, LIU Jin-dun2   

  1. 1.College of Chemistry and Chemical Engineering,Guangxi NormalUniversity,Guilin Guangxi 541004,China;
    2.College of Chemical Engineering and Energy,Zhengzhou University,Zhengzhou Henan 450001,China
  • Received:2010-10-31 Published:2018-11-19

摘要: 通过表面化学法将阴离子聚丙烯酰胺接枝到醋酸纤维素微滤膜上,得到聚电解质改性膜。实验研究了阴离子聚丙烯酰胺质量分数、交联剂质量分数、交联反应温度和反应时间对接枝率、改性膜的水通量和截留率的影响。结果表明,聚电解质质量分数越高、交联剂质量分数越大、反应时间越长、反应温度越高,膜的水通量越低而截留率越高。

关键词: 表面化学法, 阴离子聚丙烯酰胺, 醋酸纤维素微滤膜

Abstract: The cellulose acetate (CA) microporous membranes weremodified by chemical surface-grafted method with anionic polyacrylamide.The effects of concentration of anionic polyacrylamide and cross-linking agent,reaction time and temperature on grafting yield and the flux and rejection of graftedmembrane were investigated.The results show that the flux of modified membranesdecreased while the rejection increased with increasing concentration of anionicpolyacrylamide and cross-linking agent,extending reaction time,raising reaction temperature.

Key words: chemical surface-grafted method, anionic polyacrylamide, microporous cellulose acetate membrane

中图分类号: 

  • TQ316.6
[1] 徐铜文.膜化学与技术教程[M].合肥:中国科学技术大学出版社,2003.
[2] PETERSON E S,STONE M L,CUMMINGS D G,et al.Separations of hazardousorganics from gas and liquid feedstreams using phosphazene polymer membrane[J].Separation Science and Technology,1993,28(1/3):271.
[3] 戴清文.聚电解质表面修饰聚丙烯微孔膜的研究[D].杭州:浙江大学材料与化工学院,2004.
[4] 王宏琳,杨大令,张守海,等.分离丙烯/丙烷的超薄聚电解质中空纤维复合膜的制备[J].应用化学,2007,24(3):241-244.
[5] 苗晶,陈国华,高从土皆,等.戊二醛交联的壳聚糖硫酸酯/聚砜复合膜的制备及截留性能[J].高校化学工程学报,2007,21(2):227-232.
[6] 相里粉娟,金万勤,徐南平.盐酸溶液通过交替沉积的聚电解质自组装多层膜的渗透实验研究[J].高校化学工程学报,2005,19(4):445-449.
[7] LIU Zhen-mei,XU Zhi-kang,WAN Ling-shu,et al.Surface modification of polypropylene microfiltration membranes by the immobilization of poly(N-vinyl-2-pyrrolidone):a facile plasma approach[J].Journal of Membrane Science,2005,249(1):21-31.
[8] ABDUL H M Y,MATHIAS U.Polypropylene-based membrane adsorbers viaphoto-initiated graft copolymerization:optimizing separation performance by preparation conditions[J].Jouranl of Membrane Science,2008,311(1/2):294-305.
[9] 张开.高分子界面科学[M].北京:中国石化出版社,1997.
[10] CESAR L P,JOSEMAR S,LUCIANE L M,et al.Cationic quaternary polyelectrolytes based on dialkylarninoisoprenes[J].Polymer Bulletin,2000,44(5/6):477-484.
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