广西师范大学学报（自然科学版） ›› 2022, Vol. 40 ›› Issue (5): 183-198.doi: 10.16088/j.issn.1001-6600.2021112707

• 综述 • 上一篇    下一篇

原位拉曼光谱研究电催化反应过程

阿尧林1, 王耀辉2, 董金超1*, 李剑锋1,2   

  1. 1.厦门大学 能源学院, 福建 厦门 361102;
    2.厦门大学 化学化工学院, 福建 厦门 361005
  • 收稿日期:2021-11-27 修回日期:2022-04-01 出版日期:2022-09-25 发布日期:2022-10-18
  • 通讯作者: 董金超(1987—), 男, 安徽阜阳人, 厦门大学副教授, 博导。 E-mail: jcdong@xmu.edu.cn
  • 基金资助:
    国家重点研发计划(2020YFB1505800, 2019YFA0705400); 国家自然科学基金(21925404, 21902137); 厦门大学校长基金(20720210043)

In-situ Raman Spectroscopy Study of Electrocatalytic Reaction Process

A Yaolin1, WANG Yaohui2, DONG Jinchao1*, LI Jianfeng1,2   

  1. 1. College of Energy, Xiamen University, Xiamen Fujian 361102, China;
    2. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen Fujian 361005, China
  • Received:2021-11-27 Revised:2022-04-01 Online:2022-09-25 Published:2022-10-18

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摘要： 面对日益严重的环境污染和能源危机,开发高效清洁的能源转换技术受到人们广泛的关注。以电催化为代表的电化学能源转换技术由于高效且无污染,近些年获得快速发展。然而,固/液界面电催化反应涉及多种反应物种,使得其机理解释非常困难,限制了高效电催化剂的理性设计和开发。电化学原位增强拉曼光谱技术具有灵敏度高、选择性好、指纹识别的优点,可以从分子原子水平揭示电催化反应过程。本文综述电化学原位增强拉曼光谱在一些重要电催化反应研究中的应用,包括氧还原反应、氢氧化反应、氧析出反应、氢析出反应、二氧化碳还原反应过程等。最后,总结原位增强拉曼光谱技术在电催化反应研究中面临的一些问题,并对其发展进行简要展望。

关键词: 原位增强拉曼光谱, 电催化, 反应机理, 中间物种

Abstract: Faced with the increasingly severe environmental pollution and energy crisis, the development of efficient and clean energy conversion technology has attracted more attention. Electrochemical energy conversion technology represented by electrocatalysis has developed rapidly in recent years because of its high efficiency and no pollution. However, the electrocatalytic reaction at the solid/liquid interface involves a variety of reaction species, which makes its mechanism research very difficult, and limits the rational design and development of high-efficiency electrocatalysts. Electrochemical in situ enhanced Raman spectroscopy has the advantages of high sensitivity, good selectivity and fingerprint recognition. It can reveal the electrocatalytic reaction process at the molecular and atomic levels. This paper reviews the application of electrochemical in situ enhanced Raman spectroscopy to study some critical electrocatalytic reactions, including oxygen reduction reaction, hydrogen oxidation reaction, oxygen evolution reaction, hydrogen evolution reaction, carbon dioxide reduction reaction, and so on. Finally, some problems faced by in situ enhanced Raman spectroscopy in the study of electrocatalytic reactions are summarized, and its development are briefly prospected.

Key words: in-situ enhanced Raman spectroscopy, electrocatalysis, reaction mechanism, intermediate species

中图分类号: 

  • O649
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