碳纳米微粒共振瑞利散射能量转移测定铬(Ⅵ)

doi:10.16088/j.issn.1001-6600.2016.01.020

Abstract

Abstract: In HAc-NaAc buffer solution containing phenanthroline (phen) as activator,cetyl trimethyl ammonium bromide (CTMAB) as a sensitizer and H₂O₂ as an oxidant,the carbon nanoparticles(CNPs)exhibited a strong SPR Rayleigh scattering peak at 423 nm. The receptor of ARS closed to the donor of CNPs with strong plasmon resonance (SPR) Rayleigh scattering (RS),the SPRRS-energy transfer (SPRRS-ET) take place,that caused the peak at 423 nm decreased,owing to the overlapping of CNPs RRS and ARS absorption spectra. The Cr(Ⅵ) exhibited strong catalytic effect on the slow reaction of ARS-H₂O₂,when the concentration of Cr(Ⅵ) increased,the concentration of ARS decreased,and the amount of SPRRS-ET decreased, as a result, the RS intensity at 423 nm increased linearly. thus,the analytical method was established for determination of trace Cr(Ⅵ). The increased intensity ΔI_{423 nm} was linear to the Cr (Ⅵ) concentration in the range of 0.004～0.16 mg/L,with a regression equation of ΔI_{423 nm} = 49 442C+65.1,and a detection limit of 8.0 μg/L Cr (Ⅵ).The SPRRS-ET assay was applied to the analysis of Cr (Ⅵ) in environmental water,with a satisfactory result.

Key words: carbon nanoparticles, Cr (Ⅵ), catalytic, Resonance Rayleigh scattering-energy transfer

CLC Number:

O657.3

LIU Qingye, WANG Hua, HUANG Danhua, HE Shihe, LI Jiao, LUO Junheng, ZHANG Xinghui, WEN Guiqing, LIANG Aihui, JIANG Zhiliang. Determination of Trace Chromium(Ⅵ) by Carbon NanoparticlesResonance Energy Transfer Rayleigh Scattering[J].Journal of Guangxi Normal University(Natural Science Edition), 2016, 34(1): 128-133.

References

[1] 杨阳,许群. 六价铬污染与健康损害研究进展[J]. 基础医学与临床,2012(8): 974-978.
[2] 刘娜,于文芳,屈静. 二苯碳酰二肼分光光度法测定饮用水中的铬(Ⅵ)[J]. 环境科学导刊,2014,33(1): 96-98.
[3] 臧运波. 催化动力学光度法测定铬(Ⅵ)的研究进展[J]. 光谱实验室,2010,27(6): 2250-2253.
[4] DIMITRAKOPOULOS I K,TSEREPA H D,THOMAIDIS N S. Analytical methods for the determination of traces of Cr(Ⅵ) in water samples with suppressed ion chromatography[J]. Analytical Letters, 2012, 45:4-6.
[5] 鲁丹,刘雅萍. 电感耦合等离子体原子发射光谱法测定痕量Cr(Ⅵ)[J]. 中国卫生检验杂志,2008,18(3): 399-412.
[6] 金献忠,谢健梅,梁帆,等. 碱熔融-电感耦合等离子体原子发射光谱法测定铬矿石中铬铝铁镁硅[J]. 冶金分析,2010(1): 29-33.
[7] 丁静,陈欣. 荧光猝灭法测定痕量铬(Ⅵ)的研究及应用[J]. 冶金分析,2009,29(10): 52-54.
[8] 葛成岩. 连续流动注射法测定地表水中六价铬的研究[J]. 化工管理,2014,6:92.
[9] 陈兰化,刘发光. 共振瑞利散射光谱法测定水中铬(Ⅵ)[J]. 中国卫生检验杂志,2006,16(2): 205-206.
[10] 蒋治良,姚东梅,李芳,等. 免疫金铂纳米合金催化共振散射光谱法测定痕量人绒毛膜促性腺激素[J]. 化学学报,2012,70(16): 1748-1754.
[11] 韦小玲,张玉兰,蒋治良. 一种检测痕量IgG的免疫纳米银共振散射光谱探针[J]. 光谱学与光谱分析,2009,29(6): 1640-1642.
[12] WEN Guiqing,LIANG Aihui,FAN Yanyan,et al.A simple and rapid resonance scattering spectral method for detection of trace Hg²⁺ using aptamer-nanogold as probe[J]. Plasmonics,2010,5(1):1-6.
[13] LUO Yanghe,XU Lili,LIANG Aihui,et al.A highly sensitive resonance Rayleigh scattering assay for detection of Hg(II) using immunonanogold as probe[J]. RSC Advances,2014,4(37):19234-19237.
[14] WANG Yaohui,ZHANG Xinghui,LIU Qingye,et al. A simple and sensitive graphene oxide/gold nanoparticle surface plasmon resonance Rayleigh scattering-energy transfer analytical platform for detection of iodide and H₂O₂[J]. RSC Adv,2015,5(12): 9272-9277.
[15] 饶建顺. 炭黑颜料型中性墨水配方及工艺研究[D]. 广州:广州大学,2012.
[16] 蒋治良,刘绍璞,刘庆业. 碳纳米微粒的共振散射光谱研究[J]. 应用化学,2002,19(1): 22-25.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

Comments

Recommended 10

[1]	MENG Chunmei, LU Shiyin, LIANG Yonghong, MO Xiaomin, LI Weidong, HUANG Yuanjie, CHENG Xiaojing, SU Zhiheng, ZHENG Hua. Electron Microscopy Study on the Apoptosis and Autophagy of the Hepatic Stellate Cells Induced by Total Alkaloids[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 76 -79 .
[2]	LI Yuhui, CHEN Zening, HUANG Zhonghao, ZHOU Qihai. Activity Time Budget of Assamese macaque (Macaca assamensis) during Rainy Season in Nonggang Nature Reserve, Guangxi, China[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 80 -86 .
[3]	QIN Yingying, QI Guangchao, LIANG Shichu. Effects of Eichhornia crassipes Aqueous Extracts on Seed Germination of Ottelia acuminata var. jingxiensis[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 87 -92 .
[4]	ZHUANG Fenghong, MA Jiangming, ZHANG Yajun, SU Jing, YU Fangming. Eco-Physiological Responses of Leaves of Isoetes sinensis to Light Intensity[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 93 -100 .
[5]	WEI Hongjin, ZHOU Xile, JIN Dongmei, YAN Yuehong. Additions to the Pteridophyte Flora of Hunan, China[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 101 -106 .
[6]	BAO Jinping, ZHENG Lianbin, YU Keli, SONG Xue, TIAN Jinyuan, DONG Wenjing. Skinfold Thickness Characteristics of Yi Adults in Daliangshan,China[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 107 -112 .
[7]	LIN Yongsheng, PEI Jianguo, ZOU Shengzhang, DU Yuchao, LU Li. Red Bed Karst and Its Hydrochemical Characteristics of Groundwater in the Downstream of Qingjiang River, China[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 113 -120 .
[8]	ZHANG Ru, ZHANG Bei, REN Hongrui. Spatio-temporal Dynamics Analysis and Its Affecting Factors of Cropland Loss in Xuangang Mining Area, Shanxi, China[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 121 -132 .
[9]	LI Xianjiang, SHI Shuqin, CAI Weimin, CAO Yuqing. Simulation of Land Use Change in Tianjin Binhai New Area Based on CA-Markov Model[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 133 -143 .
[10]	WANG Mengfei, HUANG Song. Spatial Linkage of Tourism Economy of Cities in West River Economic Belt in Guangxi, China[J]. Journal of Guangxi Normal University(Natural Science Edition), 2018, 36(3): 144 -150 .

Determination of Trace Chromium(Ⅵ) by Carbon NanoparticlesResonance Energy Transfer Rayleigh Scattering

PDF (PC)

Abstract

Cite this article

share this article

References

Related Articles 4

Metrics

Comments

Recommended 10

[1]	LI Lihong, FANG Zhigang, ZHAO Zhenning, CHEN Lin, HAN Jianming, CUI Yuandong, MA Tianqi,JIANG Yuchen. Catalytic Properties of Cluster Ni₃CoP in the Hydrogen Evolution Reaction [J]. Journal of Guangxi Normal University(Natural Science Edition), 2019, 37(1): 165-172.
[2]	ZHONG Xin-xian, WANG Zhi-hong, YIN Xiao-ling, WANG Yan-jun, HUANGHan-xing, FENG Qi-peng. Electrocatalytic Performance of Platinum-modified PAni/PTn Composite Electrode toward Methanol Oxidation [J]. Journal of Guangxi Normal University(Natural Science Edition), 2012, 30(4): 75-80.
[3]	CHEN Meng-lin, SU Cheng-yuan, WANG Jian, HE Xing-cun, HUANG Zhi. Treatment of Reactive Brilliant Blue K-3R Dye Wastewater by Improved Inner Electrolytic-Photocatalytic [J]. Journal of Guangxi Normal University(Natural Science Edition), 2012, 30(3): 224-229.
[4]	TANG Mei-ling, LIANG Ai-hui, LIU Qing-ye, JIANG Zhi-liang. Nanocatalytic Spectrophotometric Determination of Palladium(Ⅱ)Using NiCl₂-NaH₂PO₂ System [J]. Journal of Guangxi Normal University(Natural Science Edition), 2011, 29(3): 47-51.