Journal of Guangxi Normal University(Natural Science Edition) ›› 2015, Vol. 33 ›› Issue (4): 87-95.doi: 10.16088/j.issn.1001-6600.2015.04.015

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A Comparative Study on Salt Solubility, Densities and Refractive Indices in Ternary Systems Composed of Alkali Metal (Na, K, Rb, and Cs) Nitrate, Alcohol, and Water

ZHANG Hui-ying, LIU Rui-qiang   

  1. School of Environment and Natural Resources, The Ohio State University, Columbus, OH 43210, United States
  • Received:2015-05-27 Online:2015-12-25 Published:2018-09-21

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Abstract: This paper reports the changes of salt solubility, solution density and the solution refractive index (RI) with changes of the alcohol concentration (mass fraction covering a wide range of 0~100%) in ternary solution systems composed of alkali metal (Na, K, Rb, or Cs, respectively) nitrate, alcohol (ethylene glycol, 1, 2-propanediol or glycerol, respectively) and water at different temperatures. Experimental results from the saturated systems showed that the salt solubility and solution density generally decreased with the increase of alcohol content in a system while the changing trend of RI with alcohol was just the opposite. Moreover, alcohols containing more hydroxyl groups usually resulted in higher salt solubility, solution density and solution RI than those containing less of this group. In addition, temperature tested in a range from 288 to 318 K had little impact on these parameters of the ternary systems. This report provides the basic experimental data on the primary physicochemical properties of alkali metal salts-alcohol-water ternary systems, which are important for industrial applications of alkali metal salts separation and purification among others.

Key words: alkali metal nitrade, salting-out rate, density, refractive index, alcohol

CLC Number: 

  • O616
[1] 许新, 朱屯. 碱土金属溶剂萃取分离的新进展[J]. 化工进展, 2000(1): 24-27.
[2] BRENNER D K, ANDERSON E W, LYNN S, et al. Liquid-liquid eequilibria for saturated aqueous solutions of sodium sulfate +1-propanol, 2-propanol, or 2-methylpropan-2-01[J]. J Chem Eng Data, 1992, 37: 419-422.
[3] MOSSER I S, ALFASS Z B. Separation of the KX-KXO3-KXO4(X=Cl, Br, I) system by solventing-out process[J]. Sep Sci Tech, 1983, 18: 165-172.
[4] 陈海涛, 未作君, 元英进. 红豆杉细胞两液相体系中紫杉醇的分离研究[J]. 化学工业与工程, 2001, 18(2): 99-102.
[5] 刘晓峰, 邓修. 提高灰黄霉素溶解度的研究[J]. 中国抗生素杂志, 1999, 24(6): 417-418.
[6] 李永安, 韩小红. 蛋黄磷脂的提纯[J]. 应用化工, 2003, 32(3): 60-61.
[7] 张维昊, 金丽娜, 徐小清. 鱼肉中微囊藻毒素的高效液相色谱法分析[J]. 分析科学学报, 2001, 17(2): 117-119.
[8] 张金娥. 毛细管柱气相色谱法测定食品中农药残留量的研究[D]. 济南:山东师范大学, 2003: 36-42.
[9] 李美蓉, 袁存光. 萃取-反萃取导数光谱法测定污水中微量酚和苯胺类[J]. 中国环境科学, 1998, 18(5): 427-429.
[10] 彭宣钧, 李其祥. 低哇琳不溶物含量煤沥青的研制及其炭化行为探讨[J]. 武汉钢铁学院学报, 1994, 17(3): 261-266.
[11] 袁新华, 范健, 秦志宏. CZS-NMP混合溶剂中煤萃取率的研究[J]. 煤炭转化, 1998, 21(2): 60-62.
[12] 陈京闽, 吴学勤. 混合溶剂萃取-火焰原子吸收法测定水中铜的研究[J]. 中国卫生检验杂志, 1998, 8(4): 249-250.
[13] REDDY B R, SARMA P V R B. Extraction of iron(Ⅲ) at macro-level concentrations using TBP, MIBK and their mixtures[J]. Hydrometallurgy, 1996, 43: 299-306.
[14] FLEYTLIEH I U, SERGEEV V V, PASHKOV G L, et al. Purification of cobalt solutions from manganese by extraction with mixture of organic acids[J]. Miner Process Extr Metall Rev, 1995, 15: 166-167.
[15] DINIZA M C T, FILHOB O F, ROHWEDDER J J R. An automated system for liquid-liquid extraction based on a new micro-batch extraction chamber with on-line detection: preconcentration and determination of copper(Ⅱ) [J]. Anal Chim Acta, 2004, 525: 281-287.
[16] BUCH A, STAMBOULI M, PARAEAU D, et al. Solvent extraction of nickel(Ⅱ) by mixture of 2-ethylheanal oxime and bis (2-ehtylhexyl) phosphoric acid[J]. Solvent Extr Ion Exch, 2002, 20: 49-66.
[17] KINLSHITA T, AKITA S, NII S, et al. Application of hydrofluoroehters as diluent to solvent extraction of zinc (Ⅱ) using phosphorus acid exrtactants[J]. J Chem Eng Jpn, 2005, 38: 94-99.
[18] 张运明, 唐亚贤, 刘幽燕, 等. 废水中甲酸萃取回收的研究[J]. 化工环保, 1900, 16(1): 3-8.
[19] 杨义燕, 党广悦, 王陈, 等. 络合萃取法处理癸二酸生产中的含酚废水[J]. 化工环保, 1997, 17(3): 135-139.
[20] 朱慎林, 朴香兰. 萃取-蒸馏法处理与回收糠醛废水中醋酸的研究[J]. 水处理技术, 2002, 28(4): 200-202.
[21] 伍志春, 廖晓星, 陈家铺. 甲基环己烷-正庚烷-混合溶剂体系的相平衡及溶剂抽提性能[J]. 化工冶金, 2000, 21(2): 118-122.
[22] INCI I, USLU H. Extraction of glycolic acid from aqueous solutions by trioctyl methylammonium chloride and organic solvents[J]. J Chem Eng Data, 2005, 50: 536-540.
[23] 秦炜, 曹雁青, 戴酞元. 络合萃取法从稀溶液中提取草酸[J]. 高校化学工程学报, 2001, 15(3): 282-285.
[24] 杨义燕, 王陈, 王芹珠,等. 磷酞胺类化合物萃取醋酸[J]. 应用化学, 1998, 15(2): 36-39.
[25] DENG Tian-long, LI Dong-chan. Solid liquid metastable equilibria in the quaternary system NaCl-KCl-CaCl2-H2O at 288.15 K[J]. Fluid Phase Equilib, 2008, 269: 98-103.
[26] 阎树旺, 唐明林, 邓天龙. 三元体系 KCl-K2B4O7-H2O 25 K 时相平衡研究[J]. 矿物岩石, 1994, 14(1): 101-103.
[27] 阎树旺, 唐明林, 邓天龙. 三元体系NaCl-Na2B4O7-H2O 25 K相平衡研究[J]. 海湖盐与化工, 1993, 22(5): 7-9.
[28] JOHN W. Encyclopedia of chemical technology[M]. New York: Wiley Interscience Publication, 1997.
[29] 陈瑶, 李任强, 田村和弘. 1-乙氧基-2-丙醇/水/癸烷的液液平衡[J]. 化工学报, 2003, 54(10): 1463-1465.
[30] 倪力军, 郑荣, 张立国. 天然产物液液萃取的模拟计算[J]. 计算机与应用化学, 2002, 19(5): 622-624.
[31] 阿格·弗雷登斯隆德. UNIFAC功能团法推算汽-液平衡[M]. 北京: 化学工业出版社, 1982: 5-18.
[32] LETCHER T M, REDDY P. Ternary (liquid + liquid) equilibria for mixtures of 1-hexyl-3-methylimidazolium (tetrafluoroborate or hexafluorophosphate) + benzene + an alkane at T = 298.2 K and P = 0.1 MPa[J]. J Chem Thermodyn, 2005, 37: 415-421.
[33] McDONALD R Q, MUIR D M. Pressure oxidation leaching of chalcopyrite: part Ⅱ: comparison of medium temperature kinetics and products and effect of chloride ion[J]. Hydrometallurgy, 2007, 86: 206-220.
[34] ZHANG Y, LI Z B. Solubilities of triethanolamine hydrochloride ionic liquid in aqueous hydrochloric acid solutions with concentrations from (0 to 8.37) mol·kg-1[J]. J Chem Eng Data, 2010, 55: 4434-4439.
[35] AZIMI G, PAPANGELAKIS V G. Thermodynamic modeling and experimental measurement of calcium sulfate in complex aqueous solutions[J]. Fluid Phase Equilib, 2010, 290: 88-94.
[36] ANDREWS B A, ASENJO J A. In protein purification methods[M]. Oxford: A Practical Approach, IRL Press, 1989.
[37] ALBERTSSON P A. Partition of cell particles and macromolecules[M]. New York: John Wily and Sons, 1986.
[38] ZASLAVSKY B. Aqueous two phase partitioning physical and bioanlytical applications[M]. New York: Maarcal Dekker, 1995.
[39] ANDERSON E W, LYNN S, PRAUSNITZ J M. Liquid-liquid equibria for 1-propanol, 2-propanol or methylpropanol[J]. J Chem Eng Data, 1992, 37: 419-422.
[40] KORIN E, SOLIFER L. Solubility of potassium dichromate in dilute aqueous ethanol solution in the temperature range 283 K to 303 K[J]. J Chem Eng Data, 1997, 42: 1251-1253.
[41] ZHANG Hui-ying, LI Shu-ni, ZHAI Quan-guo, et al. Solubilities, densities and rrefractive indices for the ternary systems 1,2-propylene glycol+MNO3+H2O(M=Na, K, Rb, Cs) at (25 and 35)℃[J]. Chem Eng Commun, 2014, 201: 323-337.
[42] ZHANG Hui-ying, LI Shu-ni, ZHAI Quan-guo, et al. Equilibrium phase behavior of ethylene glycol /glycerin + RbNO3/CsNO3 + H2O at (288.15 and 298.15) K[J]. Chem Res Chin Univ, 2014, 30: 978-986.
[43] ZHANG Hui-ying, LI Shu-ni, ZHAI Quan-guo, et al. Phase equilibria of alkali metal salt (NaNO3,KNO3,RbNO3,CsNO3) in system HOCH2CH(OH)CH2OH-H2O at various temperatures[J]. J Chem Chem Eng, 2014, 63: 155-162.
[44] 张晖英, 李淑妮, 翟全国, 等. 碱金属硝酸盐在1,2-丙二醇-水混合溶剂中15℃和45℃的溶液行为研究[J]. 华东师范大学学报: 自然科学版, 2013 (5): 88-95.
[45] 张晖英, 李淑妮, 翟全国, 等. 三元体系CH2OHCH2OH+NaNO3 /KNO3+H2O 在15 ℃和 25 ℃下的溶解度、密度和折光率研究[J]. 广西大学学报: 自然科学版, 2013, 38(3): 507-514.
[46] LI Shu-ni, HU Man-cheng, JIN Hua, et al. Solubility of rubidium nitrate in CH3OH or C2H5OH aqueous solutions at different temperaturas[J]. Chin J Chem, 2005, 23: 1348-1354.
[47] HU Man-cheng, ZHAI Quan-guo, JIANG Yu-cheng, et al. Liquid-liquid and liquid-liquid-solid equilibrium in PEG+Cs2SO4+H2O[J]. J Chem Eng Data, 2004, 49: 1440-1443.
[48] HO-GUTIERREZ I, CHELUGET E, VERA J, et al. Liquid-liquid equilibrium of aqueous mixtures of poly(ethy1ene glycol) with Na2SO4 or NaCl[J]. J Chem Eng Data, 1994, 39: 245-248.
[49] HU Man-cheng, JIN Li-hua, JIANG Yu-cheng, et al. Solubility of cesium nitrate in aqueous alcohol solutions at (25, 35, and 45) ℃[J]. J Chem Eng Data, 2005, 50: 1361-1364.
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