广西师范大学学报（自然科学版） ›› 2018, Vol. 36 ›› Issue (2): 78-86.doi: 10.16088/j.issn.1001-6600.2018.02.011

• • 上一篇    下一篇

羧酸盐型Gemini表面活性剂的表面性能研究

吴娟,邹华*,梅平   

  1. 长江大学化学与环境工程学院,湖北荆州 434023
  • 收稿日期:2017-07-04 出版日期:2018-05-10 发布日期:2018-07-18
  • 通讯作者: 邹华(1977—),女,湖北荆州人,长江大学讲师。E-mail:70401773@qq.com
  • 基金资助:
    国家自然科学基金(21403017);中国石油科技创新基金(2011D-5006-0211)

Surface Properties of Carboxylate Gemini Surfactant

WU Juan,ZOU Hua*,MEI Ping   

  1. College of Chemistry and Environmental Engineering,Yangtze University,Jingzhou Hubei 434023,China
  • Received:2017-07-04 Online:2018-05-10 Published:2018-07-18

PDF (PC)

471

摘要： 采用铂金板法测定羧酸盐型Gemini表面活性剂(CGS-12)的表面张力曲线,考察了溶液pH、无机盐以及醇的加入对CGS-12表面性能的影响规律,采用滴体积法测定CGS-12 的动态表面张力曲线,并探讨其动态吸附机理。结果表明,CGS-12的临界胶束浓度(cmc)和临界表面张力(γcmc)分别为80 μmol/L和26.37 mN/m;当溶液pH值为6时,CGS-12的表面张力值最低,且其表面张力随溶液pH的变化具有可逆性;CGS-12的表面张力随NaCl浓度的增大先减小后增大,CGS-12的表面张力随着CaCl2浓度的增大先增大后基本不变;CGS-12的表面活性随着正丁醇浓度的增大而增加,随着醇碳链长度的增加,cmc的变化并不明显,但γcmc却明显降低;动态表面张力结果表明,CGS-12浓度较低时,吸附初期为扩散控制,吸附后期为混合动力学控制,浓度较高时,吸附初期曲线难以模拟,吸附后期为混合动力学控制。

关键词: 羧酸盐型Gemini表面活性剂, 表面活性, 表面张力, 抗盐性能, 动态吸附

Abstract: The surface tension curve of carboxylate Gemini surfactant (CGS-12) was measured using the platinum plate method. The effects of pH value, the addition of inorganic salts and alcohols on the surface properties of CGS-12 were investigated. In addition,the dynamic surface tension curve of CGS-12 was measured using drop volume method,and the dynamic adsorption mechanism was also explored. The results show that the cmc and γcmc of CGS-12 are 80 μmol/L and 26.37 mN/m, respectively. The adjustment of pH value of solution leads to a reversible change of the surface tension of CGS-12 which reaches the minimal at the pH value of 6. Increasing the concentration of NaCl, the surface tension of CGS-12 decreases first and then increases. However, the surface tension of CGS-12 undergoes an increase before reaching a plateau as the concentration of CaCl2 is increased. The surface activity of CGS-12 increases with the increasing concentration of n-butanol. Increasing the carbon chain lengths of the alcohol, γcmc decreases significantly with no obvious variation for cmc. The results of the dynamic surface tension show that the adsorption at low concentration of CGS-12 is controlled by diffusion at the beginning and then a mixed kinetic-diffusion adsorption mechanism toward the end. At higher concentration of CGS-12, the adsorption process is controlled by the mixed kinetic-diffusion adsorption mechanism for the later stage although it can’t be simulated at the initial stage.

Key words: carboxylate Gemini surfactant, surface activity, surface tension, salt resistance, dynamic adsorption

中图分类号: 

  • TQ423
[1] ZHU Yunpeng,MASUYAMA A,KOBATA Y,et al. Double-chain surfactants with two carboxylate groups and their relation to similar double-chain compounds[J]. Journal of Colloid and Interface Science,1993,158(1): 40-45.
[2] 高志农,许东华,吴晓军. 新型低聚表面活性剂研究进展[J]. 武汉大学学报 (理学版),2004,50(6):691-697.
[3] TSUBONE K,GHOSH S. Micellization of an anionic gemini surfactant having N,N-dialkylamide,carboxyl,and carboxylate groups in aqueous NaCl solutions[J]. Journal of Surfactants and Detergents,2004,7(1):47-52.
[4] 杜恣毅,游毅,姜蓉,等. 含对苯氧基联接链的羧酸盐 Gemini 表面活性剂合成及胶团化特性[J].高等学校化学学报,2003,24(11):2056-2059.
[5] 黄艺雄. 含羧酸盐 Gemini 成分的正/负离子表面活性剂混合体系聚集体形貌的研究[D]. 福州:福州大学,2006.
[6] 谢丹华. 含长刚性联接链的羧酸盐Gemini表面活性剂在水溶液中的聚集行为:光散射和流变学研究[D]. 福州:福州大学,2013.
[7] 刘芬. 添加剂对含长刚性联接链的羧酸盐 Gemini 表面活性剂聚集行为的影响[D]. 福州:福州大学,2014.
[8] XIE Danhua,ZHAO Jianxi. Unique aggregation behavior of a carboxylate gemini surfactant with a long rigid spacer in aqueous solution[J]. Langmuir,2012,29(2): 545-553.
[9] YOSHIMURA T,BONG M,MATSUOKA K,et al. Surface properties and aggregate morphology of partially fluorinated carboxylate-type anionic gemini surfactants[J]. Journal of Colloid and Interface Science,2009,339(1): 230-235.
[10] LAI Lu,MEI Ping,LIU Yi,et al. Micellization of anionic gemini surfactants and their interaction with polyacrylamide[J]. Colliod Polym Sci,2014,292: 2821-2830.
[11] 印永嘉. 物理化学简明手册[M]. 北京:高等教育出版社,1988:374.
[12] XIAO J X,ZHAO Z G. Application principle of surfactants[M]. Beijing: Chemical Industry Press,2003: 496.
[13] 张莹,陈莉,肖进新,等. 高浓度无机盐对正负离子等摩尔混合表面活性剂表面活性的影响[J].化学学报,2004,62(16):1491-1494.
[14] SREEJITH L,PARATHAKKAT S,NAIR S M,et al. Octanol-triggered self-assemblies of the CTAB/KBr system: a microstructural study[J]. The Journal of Physical Chemistry B,2010,115(3): 464-470.
[15] 唐永强,朱琳一,韩玉淳,等. 支链醇对 Gemini 表面活性剂表面活性和胶束化行为的影响[J]. 化学学报,2014,72(6):673-681.
[16] HUANG J B,MAO M,ZHU B Y. The surface physico-chemical properties of surfactants in ethanol-water mixtures[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,1999,155(2):339-348.
[17] FAINERMAN V B,MAKIEVSKI A V,MILLER R. The analysis of dynamic surface tension of sodium alkyl sulphate solutions,based on asymptotic equations of adsorption kinetic theory[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1994, 87(1):61-75.
[18] LIGGIERI L,RAVERA F,PASSERONE A. A diffusion-based approach to mixed adsorption kinetics[J].Colloid Surf A,1996,114: 351-359.
[19] ROSEN M J,SONG L D. Dynamic surface tension of aqueous surfactant solutions 8. Effect of pacer on dynamic properties of gemini surfactant solutions[J]. J Colloid Interface Sci,1996,179:261-263.
[20] 陈文君,李干佐,柴金岭,等. 十八烷基二甲基氯化铵水溶液动态表面张力及吸附动力学研究[J]. 化学学报,2002,60(4):669-673.
[21] 王虎山. 新型含三嗪环 Gemini 表面活性剂的物理化学性能研究[D]. 太原:中北大学,2012.
[1] 胡晓熙,王芸,文丰,廖丹葵,童张法. 全氟两性表面活性剂与蛋白质相互作用研究[J]. 广西师范大学学报（自然科学版）, 2018, 36(1): 105-111.
[2] 杨达, 苏春华, 赵志才, 田小艳, 潘英明, 王恒山. 脱氢松香酰二胺表面活性剂的合成及性能研究[J]. 广西师范大学学报（自然科学版）, 2012, 30(1): 55-59.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
版权所有 © 广西师范大学学报（自然科学版）编辑部
地址：广西桂林市三里店育才路15号　邮编：541004
电话：0773-5857325　E-mail: gxsdzkb@mailbox.gxnu.edu.cn
本系统由北京玛格泰克科技发展有限公司设计开发